Carbonylation reaction Communication 11. Carbonylation of amino alcohols and some cyclic amines with carbon monoxide in the presence of mercuric acetate

1973 ◽  
Vol 22 (7) ◽  
pp. 1486-1488 ◽  
Author(s):  
B. K. Nefedov ◽  
N. S. Sergeeva ◽  
Ya. T. Eidus
Keyword(s):  
Carbon Monoxide ◽  
Mercuric Acetate ◽  
Amino Alcohols ◽  
Cyclic Amines ◽  
Carbonylation Reaction ◽  
Reaction Communication

Carbonylation reaction Communication 13. Reaction of carbon monoxide with trialkylboranes

1973 ◽  
Vol 22 (8) ◽  
pp. 1760-1763 ◽  
Author(s):  
K. V. Puzitskii ◽  
S. D. Pirozhkov ◽  
K. G. Ryabova ◽  
I. V. Pastukhova ◽  
Ya. T. �idus
Keyword(s):  
Carbon Monoxide ◽  
Carbonylation Reaction ◽  
Reaction Communication

Palladium-catalyzed carbonylation of 1,5-cyclooctadiene. Effects of temperature and pressure

1991 ◽  
Vol 56 (3) ◽  
pp. 663-672 ◽  
Author(s):  
Curtis B. Anderson ◽  
Rade Marković
Keyword(s):  
Carbon Monoxide ◽  
Oxidative Carbonylation ◽  
Influence Of Temperature ◽  
Carbonylation Reaction ◽  
Palladium Catalyzed ◽  
Effects Of Temperature ◽  
Temperature And Pressure

The influence of temperature and carbon monoxide pressure on the course of oxidative carbonylation reaction of 1,5-cyclooctadiene in the presence of the palladium(II) salts as a catalyst, was investigated.

Electron-Transfer-Induced Intramolecular Heck Carbonylation Reactions Leading to Benzolactones and Benzolactams

Synthesis ◽  
2018 ◽  
Vol 50 (15) ◽  
pp. 3015-3021 ◽  
Author(s):  
Ilhyong Ryu ◽  
Takahide Fukuyama ◽  
Takanobu Bando
Keyword(s):  
Carbon Monoxide ◽  
Electron Transfer ◽  
Nucleophilic Attack ◽  
Metal Catalyst ◽  
Radical Anions ◽  
Chain Mechanism ◽  
Benzyl Alcohols ◽  
Carbonylation Reaction ◽  
Catalyst Free ◽  
Acyl Radicals

A metal-catalyst-free intramolecular Heck carbonylation reaction of benzyl alcohols and benzyl amines with carbon monoxide under heating at 250 °C affords the corresponding benzolactones and benzolactams in good to excellent yields. A hybrid radical/ionic chain mechanism, involving electron transfer from radical anions generated by nucleophilic attack of alcohols or amines on intermediate acyl radicals, is proposed.

ChemInform Abstract: Copper Catalyzed Synthesis of Cyclic Amines from Amino-Alcohols.

1986 ◽  
Vol 17 (22) ◽  
Author(s):  
W. HAMMERSCHMIDT ◽  
A. BAIKER ◽  
A. WOKAUN ◽  
W. FLUHR
Keyword(s):  
Amino Alcohols ◽  
Cyclic Amines

Ring Expansion of Cyclic β-Amino Alcohols Induced by Diethylaminosulfur Trifluoride: Synthesis of Cyclic Amines with a Tertiary Fluorine at C3

2012 ◽  
Vol 77 (14) ◽  
pp. 6087-6099 ◽  
Author(s):  
Bruno Anxionnat ◽  
Benoit Robert ◽  
Pascal George ◽  
Gino Ricci ◽  
Marc-Antoine Perrin ◽  
...  
Keyword(s):  
Ring Expansion ◽  
Amino Alcohols ◽  
Cyclic Amines

scholarly journals Catalyst Initiation in the Oscillatory Carbonylation Reaction

2011 ◽  
Vol 2011 ◽  
pp. 1-11 ◽  
Author(s):  
Katarina Novakovic ◽  
Julie Parker
Keyword(s):  
Carbon Monoxide ◽  
Chemical Reactions ◽  
Potassium Iodide ◽  
Significant Role ◽  
Reaction Network ◽  
Oxidative Carbonylation ◽  
Heat Of Reaction ◽  
Oscillatory Reaction ◽  
Oscillatory Behaviour ◽  
Carbonylation Reaction

Palladium(II) iodide is used as a catalyst in the phenylacetylene oxidative carbonylation reaction that has demonstrated oscillatory behaviour in both pH and heat of reaction. In an attempt to extract the reaction network responsible for the oscillatory nature of this reaction, the system was divided into smaller parts and they were studied. This paper focuses on understanding the reaction network responsible for the initial reactions of palladium(II) iodide within this oscillatory reaction. The species researched include methanol, palladium(II) iodide, potassium iodide, and carbon monoxide. Several chemical reactions were considered and applied in a modelling study. The study revealed the significant role played by traces of water contained in the standard HPLC grade methanol used.

A new synthesis of heterocycles by the reaction of amino alcohols or amino thiols with carbon monoxide in the presence of selenium

1975 ◽  
Vol 16 (24) ◽  
pp. 1969-1972 ◽  
Author(s):  
Noboru Sonoda ◽  
Goro Yamamoto ◽  
Kazuki Natsukawa ◽  
Kiyoshi Kondo ◽  
Shinji Murai
Keyword(s):  
Carbon Monoxide ◽  
Amino Alcohols ◽  
New Synthesis
Sign in / Sign up

Export Citation Format

Share Document