Reaction of ethyl vinyl sulfide and divinyl sulfide with triethyl- and triethoxysilane

1979 ◽  
Vol 28 (2) ◽  
pp. 389-393
Author(s):  
M. G. Voronkov ◽  
N. N. Vlasova ◽  
S. V. Kirpichenko ◽  
S. A. Vol'shakova ◽  
V. V. Keiko ◽  
...  
Keyword(s):  
Ethyl Vinyl ◽  
Vinyl Sulfide ◽  
Divinyl Sulfide

ChemInform Abstract: RADIATION-INDUCED CHEMICAL REACTION OF ETHYL VINYL SULFIDE WITH TRIETHYLSILANE

1979 ◽  
Vol 10 (34) ◽  
Author(s):  
B. I. VAINSHTEIN ◽  
S. A. BOL'SHAKOVA ◽  
N. N. VLASOVA ◽  
M. G. VORONKOV
Keyword(s):  
Chemical Reaction ◽  
Ethyl Vinyl ◽  
Vinyl Sulfide ◽  
Radiation Induced

scholarly journals Efficient Regioselective Synthesis of Novel Water-Soluble 2H,3H-[1,4]thiazino[2,3,4-ij]quinolin-4-ium Derivatives by Annulation Reactions of 8-quinolinesulfenyl Halides

Molecules ◽  
2021 ◽  
Vol 26 (4) ◽  
pp. 1116
Author(s):  
Vladimir A. Potapov ◽  
Roman S. Ishigeev ◽  
Svetlana V. Amosova
Keyword(s):  
Biological Activity ◽  
Water Soluble ◽  
Regioselective Synthesis ◽  
The Novel ◽  
Vinyl Ethers ◽  
Vinyl Sulfide ◽  
Divinyl Sulfide ◽  
Substrate Structure ◽  
Condensed Heterocycles ◽  
Phenyl Vinyl

Regioselective synthesis of novel 2H,3H-[1,4]thiazino[2,3,4-ij]quinolin-4-ium derivatives has been developed by annulation reactions of 8-quinolinesulfenyl halides with vinyl chalcogenides (vinyl ethers, divinyl sulfide, divinyl selenide and phenyl vinyl sulfide) and tetravinyl silane. The novel reagent 8-quinolinesulfenyl bromide was used in the annulation reactions. The influence of the substrate structure and the nature of heteroatoms on the direction of the reactions and on product yields has been studied. The opposite regiochemistry was observed in the reactions with vinyl chalcogenides and tetravinyl silane. The obtained condensed heterocycles are novel water-soluble functionalized compounds with promising biological activity.

Reactions of ruthenium hydrides with ethyl-vinyl sulfide

2014 ◽  
Vol 43 (9) ◽  
pp. 3501-3507 ◽  
Author(s):  
Fatme Dahcheh ◽  
Douglas W. Stephan
Keyword(s):  
Ethyl Vinyl ◽  
Vinyl Sulfide ◽  
Diethyl Sulfide ◽  
Vinyl Derivatives

Ru-hydride precursors containing the OCO-carbene ligand react with ethyl-vinyl-sulfide to give Ru alkyl and vinyl derivatives via an initial insertion of the vinyl-fragment into the Ru–H, subsequent C–H activation and loss of diethyl sulfide.

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