Replacement of heteroorganic fragment in heteroorganic derivatives of aliphatic nitro compounds

1978 ◽  
Vol 27 (4) ◽  
pp. 816-819
Author(s):  
S. L. Ioffe ◽  
A. V. Kalinin ◽  
T. N. Golovina ◽  
B. N. Khasapov ◽  
V. A. Tartakovskii
Keyword(s):  
Nitro Compounds ◽  
Aliphatic Nitro Compounds ◽  
Derivatives Of

Trimethylsilyl derivatives of aliphatic nitro compounds in α,β-C,C-cross-coupling

2000 ◽  
Vol 49 (5) ◽  
pp. 874-878 ◽  
Author(s):  
A. D. Dilman ◽  
I. M. Lyapkalo ◽  
S. L. Ioffe ◽  
Yu. A. Strelenko ◽  
V. A. Tartakovsky
Keyword(s):  
Cross Coupling ◽  
Nitro Compounds ◽  
Aliphatic Nitro Compounds ◽  
Trimethylsilyl Derivatives ◽  
Derivatives Of

ChemInform Abstract: Trimethylsilyl Derivatives of Aliphatic Nitro Compounds in α,β-C,C-Cross-Coupling.

ChemInform ◽  
2010 ◽  
Vol 31 (46) ◽  
pp. no-no
Author(s):  
A. D. Dilman ◽  
I. M. Lyapkalo ◽  
S. L. Ioffe ◽  
Yu. A. Strelenko ◽  
V. A. Tartakovsky
Keyword(s):  
Cross Coupling ◽  
Nitro Compounds ◽  
Aliphatic Nitro Compounds ◽  
Trimethylsilyl Derivatives ◽  
Derivatives Of

ChemInform Abstract: REPLACEMENT OF THE ORGANOMETALLIC FRAGMENT IN ORGANOMETALLIC DERIVATIVES OF ALIPHATIC NITRO COMPOUNDS

1978 ◽  
Vol 9 (37) ◽  
Author(s):  
S. L. IOFFE ◽  
A. V. KALININ ◽  
T. N. GOLOVINA ◽  
B. N. KHASAPOV ◽  
V. A. TARTAKOVSKII
Keyword(s):  
Nitro Compounds ◽  
Aliphatic Nitro Compounds ◽  
Derivatives Of

Trimethylsilyl derivatives of aliphatic nitro compounds in α,β-carbon–carbon cross-coupling reactions

1997 ◽  
Vol 7 (4) ◽  
pp. 133-135 ◽  
Author(s):  
Alexander D. Dilman ◽  
Il’ya M. Lyapkalo ◽  
Yuri A. Strelenko ◽  
Sema L. Ioffe ◽  
Vladimir A. Tartakovskii
Keyword(s):  
Cross Coupling ◽  
Nitro Compounds ◽  
Coupling Reactions ◽  
Aliphatic Nitro Compounds ◽  
Cross Coupling Reactions ◽  
Trimethylsilyl Derivatives ◽  
Derivatives Of

1H, 13C and 15N NMR Spectra of Coupling Products of Benzenediazonium Salts with Aliphatic Nitro Compounds and Study of Their E/Z Isomerism

1996 ◽  
Vol 61 (4) ◽  
pp. 589-596 ◽  
Author(s):  
Antonín Lyčka
Keyword(s):  
Dimethyl Sulfoxide ◽  
Nmr Spectra ◽  
Chemical Shifts ◽  
Nitro Compounds ◽  
Coupling Constants ◽  
15N Nmr ◽  
Geometrical Isomers ◽  
Sodium Salts ◽  
Aliphatic Nitro Compounds ◽  
Tautomeric Forms

The 1H, 13C and 15N NMR spectra have been measured of coupling products of benzenediazonium salts with nitromethane, nitroethane, 1-nitropropane, 2-nitroethanol and of their sodium salts, and the chemical shifts have been unambiguously assigned. The coupling products have been found to exist only in their hydrazone tautomeric forms. Stereospecific behaviour of the coupling constants 2J(15N,1H) and 2J(15N,13C) in the 15N isotopomers and NOESY have been used to differentiate between the E and Z geometrical isomers. The above-mentioned compounds exist as Z isomers in deuteriochloroform and predominantly (>95%) as E isomers in dimethyl sulfoxide, while the sodium salts are present only as E isomers in dimethyl sulfoxide.

Synthesis and antimicrobial activity of aliphatic nitro compounds

1974 ◽  
Vol 17 (9) ◽  
pp. 977-981 ◽  
Author(s):  
Nigel G. Clark ◽  
Betty Croshaw ◽  
Brian E. Leggetter ◽  
David F. Spooner
Keyword(s):  
Antimicrobial Activity ◽  
Nitro Compounds ◽  
Aliphatic Nitro Compounds

Toxicological investigations on Astragalus hamosus and Astragalus sesameus

1980 ◽  
Vol 20 (103) ◽  
pp. 162 ◽  
Author(s):  
MC Williams
Keyword(s):  
Nitro Compounds ◽  
Aliphatic Nitro Compounds ◽  
Water Extracts ◽  
Nitropropionic Acid ◽  
3 Nitropropionic Acid

Astragalus hamosus L. and Astragalus sesameus L. were examined for the presence and type of aliphatic nitro compounds and for their toxicity to 1 -week-old chicks. A. hamosus leaves assayed 10 to 11 mg of NO2 g-1 in compounds that yielded 3-nitropropionic acid upon hydrolysis. Water extracts of A. hamosus leaves were toxic to chicks at the equivalent of 3 g of dried plant per chick, and lethal at 6 to 8 g. A. sesameus did not contain nitro compounds and was non-toxic to chicks.

scholarly journals One-pot synthesis of polysubstituted indoles from aliphatic nitro compounds under mild conditions

2007 ◽  
Vol 48 (10) ◽  
pp. 1809-1811 ◽  
Author(s):  
Christopher A. Simoneau ◽  
Alexis M. Strohl ◽  
Bruce Ganem
Keyword(s):  
Nitro Compounds ◽  
One Pot ◽  
Aliphatic Nitro Compounds ◽  
Mild Conditions ◽  
One Pot Synthesis
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