Concordant mechanism for gas-phase decomposition of nitro compounds

1978 ◽  
Vol 27 (2) ◽  
pp. 411-413 ◽  
Author(s):  
V. G. Matveev ◽  
V. V. Dubikhin ◽  
G. M. Nazin
Keyword(s):  
Gas Phase ◽  
Nitro Compounds ◽  
Phase Decomposition

Mechanisms of gas phase decomposition of C-nitro compounds from quantum chemical data

2009 ◽  
Vol 78 (10) ◽  
pp. 903-943 ◽  
Author(s):  
Grigorii M Khrapkovskii ◽  
Alexander G Shamov ◽  
E V Nikolaeva ◽  
D V Chachkov
Keyword(s):  
Gas Phase ◽  
Quantum Chemical ◽  
Nitro Compounds ◽  
Chemical Data ◽  
Phase Decomposition ◽  
Quantum Chemical Data

Catalysis by hydrogen halides in the gas phase. XIX. 2,3-Dimethylbutan-2-ol and hydrogen bromide

1968 ◽  
Vol 21 (10) ◽  
pp. 2385 ◽  
Author(s):  
RL Johnson ◽  
VR Stimson
Keyword(s):  
Gas Phase ◽  
Arrhenius Equation ◽  
Hydrogen Bromide ◽  
Phase Decomposition ◽  
Hydrogen Halides ◽  
First Order

The gas-phase decomposition of 2,3-dimethylbutan-2-ol into 2,3-dimethylbut-1-ene, 2,3-dimethylbut-2-ene, and water, catalysed by hydrogen bromide at 303-400�, is described. The rate is first-order in each reactant and the Arrhenius equation k2 = 1011.88 exp(-26490/RT) sec-l ml mole-1 is followed. The olefins appear to be in their equilibrium proportions. The effects of substitutions in the alcohol at Cα and Cβ on the rate are discussed.

scholarly journals Gas-phase aluminium acetylacetonate decomposition: Revision of the current mechanism by VUV synchrotron radiation

2021 ◽  
Author(s):  
Sebastian Grimm ◽  
Seung-Jin Baik ◽  
Patrick Hemberger ◽  
Andras Bodi ◽  
Andreas Kempf ◽  
...  
Keyword(s):  
Chemical Vapor Deposition ◽  
Synchrotron Radiation ◽  
Gas Phase ◽  
Vapor Deposition ◽  
Aluminium Oxide ◽  
Chemical Vapor ◽  
Phase Decomposition ◽  
Common Precursor ◽  
Current Mechanism

Although aluminium acetylacetonate, Al(C5H7O2)3, is a common precursor for chemical vapor deposition (CVD) of aluminium oxide, its gas phase decomposition is not very well investigated. Here, we studied its thermal...

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