Mass spectra of molecules and radiation chemistry

1962 ◽  
Vol 11 (11) ◽  
pp. 1857-1864 ◽  
Author(s):  
N. N. Tunitskii ◽  
S. E. Kupriyanov ◽  
A. A. Perov
Keyword(s):  
Mass Spectra ◽  
Radiation Chemistry

E. Radiation Chemistry of Diphenylpicrylhydrazyl (DPPH), IV. The Mass Spectra of Some Aromatic Hydrazines. Comparison of Radiolytic and Photolytic Fragmentations

1976 ◽  
Vol 31 (10) ◽  
pp. 1372-1375
Author(s):  
W. G. Filby ◽  
W. H. Kalus
Keyword(s):  
Electron Impact ◽  
Mass Spectra ◽  
Radiation Chemistry ◽  
Hydrogen Migration ◽  
Radiation Induced

The mass spectra of some aryl hydrazines under electron impact are reported. In every case studied fragmentation occurs via fission of the weak hydrazyl N—N bond and hydrogen migration. Metastable ion data is presented in support of a proposed mechanism and some comparisons made between electron and radiation induced processes.

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