Carbonylation of isobutylene, its oligomers, and N-olefins by carbon monoxide in the presence of BF3 complexes with propionic, acetic or chloroacetic acids

1976 ◽  
Vol 25 (7) ◽  
pp. 1459-1465
Author(s):  
S. D. Pirozhkov ◽  
K. V. Puzitskii ◽  
T. N. Myshenkova ◽  
K. G. Ryabova ◽  
Ya. T. �idus
Keyword(s):  
Carbon Monoxide ◽  
Chloroacetic Acids

Studies on the rearrangement of (trichloromethyl)carbinols to α-chloroacetic acids

1980 ◽  
Vol 58 (5) ◽  
pp. 485-493 ◽  
Author(s):  
Wilkins Reeve ◽  
James R. McKee ◽  
Robert Brown ◽  
Sitarama Lakshmanan ◽  
Gertrude A. McKee
Keyword(s):  
Carbon Monoxide ◽  
Potassium Hydroxide ◽  
Potential Importance ◽  
Chloroacetic Acids ◽  
Aqueous Potassium Hydroxide ◽  
Mechanism Of The Reaction

Phenyl(trichloromethyl)carbinol undergoes an unimolecular, predominantly intramolecular conversion into potassium α-chlorophenylacetate on stirring with 10 % aqueous potassium hydroxide at 0 °C for several days. Besides providing an interesting example of a 1–2 chlorine shift, the reaction is of potential importance for the synthesis of α-chloro acids. The study of a variety of (trichloromethyl)carbinols shows the reaction is general for secondary (trichloromethyl)carbinols as well as trichloroethanol. The mechanism of the reaction involves the preliminary formation of an epoxide. Several mechanisms are considered for the conversion of the epoxide to the α-chloroacetate anion, but none accounts for all of the experimental facts. Tertiary carbinols break down at the epoxide stage into a ketone and carbon monoxide.

Carbon monoxide poisoning

2000 ◽  
Vol 12 (4) ◽  
pp. 354-357
Author(s):  
David R Smart ◽  
Paul D Mark
Keyword(s):  
Carbon Monoxide ◽  
Carbon Monoxide Poisoning

Infrared spectra of carbon monoxide on platinum, iridium and copper ; comparison of flat and rough surfaces

1981 ◽  
Vol 78 ◽  
pp. 927-932 ◽  
Author(s):  
F.J.C.M. Toolenaar ◽  
G.J. van der Poort ◽  
F. Stoop ◽  
V. Ponec
Keyword(s):  
Carbon Monoxide ◽  
Infrared Spectra ◽  
Rough Surfaces
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