The turbulent boundary layer in the presence of surface chemical reactions (with reference to carbon surfaces)

1971 ◽  
Vol 8 (4) ◽  
pp. 59-61
Author(s):  
E. G. Zaulichnyi ◽  
S. S. Kutateladze ◽  
A. I. Leont'ev
Keyword(s):  
Boundary Layer ◽  
Turbulent Boundary Layer ◽  
Chemical Reactions ◽  
Surface Chemical ◽  
Surface Chemical Reactions ◽  
Carbon Surfaces

SELF-SIMILAR PROBLEMS FOR MODELING THE SURFACE CHEMICAL REACTIONS WITH THE GRAVITATION

1998 ◽  
Vol 3 (1) ◽  
pp. 25-32
Author(s):  
Jânis Cepîtis ◽  
Harijs Kalis
Keyword(s):  
Boundary Layer ◽  
Mathematical Model ◽  
Differential Equations ◽  
Ordinary Differential Equations ◽  
Chemical Reactions ◽  
Glass Fibre ◽  
Surface Chemical ◽  
Self Similar ◽  
Surface Chemical Reactions ◽  
The Mathematical Model

The mathematical model of a chemical reaction which takes place on the surface of the uniformly moving vertically imbedded glass fibre material is considered. The effect of gravitation is taken into account. Boussinesq's and boundary layer fittings allow to derive boundary value problems for self‐similar systems of ordinary differential equations.

Numerical Simulation of Hydrogen-Air Boundary Layer Flows Augmented by Catalytic Surface Reactions

2007 ◽  
Author(s):  
Timothy W. Tong ◽  
Mohsen M. Abou-Ellail ◽  
Yuan Li
Keyword(s):  
Boundary Layer ◽  
Gas Phase ◽  
Boundary Layers ◽  
Chemical Reactions ◽  
Surface Chemical ◽  
Surface Species ◽  
Catalytic Surface ◽  
Platinum Surface ◽  
Surface Chemical Reactions ◽  
Volume Equations

Catalytic combustion of hydrogen-air boundary layers involves the adsorption of hydrogen and oxygen into a platinum coated surface, chemical reactions of the adsorbed species and the desorption of the resulting products. Re-adsorption of some produced gases is also possible. The catalytic reactions can be beneficial in porous burners and catalytic reactors that use low equivalence ratios. In this case the porous burner flame can be stabilized at low temperatures to prevent any substantial gas emissions, such as nitrogen oxides. The present paper is concerned with the numerical computation of heat transfer and chemical reactions in hydrogen-air mixture boundary layers that flow over platinum coated hot plates. Chemical reactions are included in the gas phase as well as on the solid platinum surface. In the gas phase, eight species are involved in 26 elementary reactions. On the platinum hot surface, additional surface species are included that are involved in 14 additional surface chemical reactions. The platinum surface temperature is fixed, while the properties of the reacting flow are computed. The flow configuration investigated in the present paper is that of a parallel boundary layer. Finite-volume equations are obtained by formal integration over control volumes surrounding each grid node. Hybrid differencing is used to ensure that the finite-difference coefficients are always positive or equal to zero to reflect the real effect of neighboring nodes on a typical central node. The finite-volume equations are solved, iteratively, for the reacting gas flow properties. On the platinum surface, surface species balance equations, under steady-state conditions, are solved numerically. A non-uniform computational grid is used, concentrating most of the nodes in the boundary sub-layer adjoining the catalytic surface. The computed OH concentration is compared with experimental and numerical data of similar geometry. The obtained agreement is fairly good, with differences observed for the location of the peak value of OH. Surface temperature of 1170 K caused fast reactions on the catalytic surface in a very small part at the leading edge of the catalytic flat plate. The computational results for heat and mass transfer and chemical surface reactions at the gas-surface interface are correlated by non-dimensional relations.

Heat and Mass Transfer From Platinum-Coated Cylinders in Axisymmetric Hydrogen-Air Boundary Layers

2008 ◽  
Author(s):  
Timothy W. Tong ◽  
Mohsen M. Abou-Ellail ◽  
Yuan Li
Keyword(s):  
Boundary Layer ◽  
Mass Transfer ◽  
Gas Phase ◽  
Chemical Reactions ◽  
Reacting Flow ◽  
Surface Chemical ◽  
Surface Species ◽  
Platinum Surface ◽  
Surface Chemical Reactions ◽  
Volume Equations

Catalytic combustion of hydrogen-air mixtures involves the adsorption of the fuel and oxidant into a platinum surface, chemical reactions of the adsorbed species and the desorption of the resulting products. Re-adsorption of some produced gases is also possible. The catalytic reactions can be beneficial in porous burners that use low equivalence ratios. In this case the porous burner flame can be stabilized at low temperatures to prevent any substantial gas emissions, such as nitric oxide. The present paper is concerned with the numerical computation of heat transfer and chemical reactions in flowing hydrogen-air mixtures axisymmetrically around a platinum-coated thin cylinder. Chemical reactions are included in the gas phase and in the solid platinum surface. In the gas phase 8 species are involved in 24 elementary reactions. On the platinum hot surface, additional surface species are included that are involved in 14 additional surface chemical reactions. The platinum surface temperature is fixed, while the properties of the reacting flow are computed. The flow configuration investigated here is the parallel boundary layer reacting flow over a cylinder. Finite-volume equations are obtained by formal integration over control volumes surrounding each grid node. Up-wind differencing is used to ensure that the influence coefficients are always positive to reflect the physical effect of neighboring nodes on a typical central node. The finite-volume equations are solved iteratively for the reacting gas flow properties. On the platinum surface, surface species balance equations, under steady-state conditions, are solved numerically by an under-relaxed linear algorithm. A non-uniform computational grid is used, concentrating most of the nodes near the catalytic surface. Surface temperatures, 1150 K and 1300 K, caused fast reactions on the catalytic surface, with very slow chemical reactions in the flowing gas. These slow reactions produce mainly intermediate hydrocarbons and unstable species. The computational results for the chemical reaction boundary layer thickness and mass transfer at the gas-surface interface are correlated by non-dimensional relations, taking the Reynolds number as the independent variable. Chemical kinetic relations for the reaction rate are obtained which are dependant on reactants concentrations and surface temperature.

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