Rupture of sulfides of the thiophene series by sodium in liquid ammonia

1960 ◽  
Vol 9 (9) ◽  
pp. 1572-1573 ◽  
Author(s):  
Ya. L. Gol'dfarb ◽  
M. A. Kalik ◽  
M. L. Kirmalova
Keyword(s):  
Liquid Ammonia ◽  
Thiophene Series

Ammonolysis of titanium tetrachloride in liquid ammonia

1976 ◽  
Vol 73 ◽  
pp. 849-851 ◽  
Author(s):  
Thomas Kottarathil ◽  
Gérard Lepoutre
Keyword(s):  
Liquid Ammonia ◽  
Titanium Tetrachloride

Studies in the thiophene series. III. Anodic oxidation of 2-thenyl alcohol

1972 ◽  
Vol 37 (8) ◽  
pp. 2584-2588 ◽  
Author(s):  
M. Janda ◽  
J. Šrogl ◽  
M. Synáčková
Keyword(s):  
Anodic Oxidation ◽  
Thiophene Series

Solubility of argon, and gaseous mixture argon-methane-nitrogen in liquid ammonia

1970 ◽  
Vol 35 (12) ◽  
pp. 3757-3761 ◽  
Author(s):  
J. Matouš ◽  
J. Šobr ◽  
J. P. Novák
Keyword(s):  
Liquid Ammonia ◽  
Gaseous Mixture

Transfer of inductive effect in thiophene series

1976 ◽  
Vol 41 (5) ◽  
pp. 1541-1550 ◽  
Author(s):  
M. Janda ◽  
J. Šrogl ◽  
M. Němec ◽  
K. Kalfus
Keyword(s):  
Inductive Effect ◽  
Thiophene Series

Preparation, properties and structure of some intermediate nido- and arachno-monocarbaboranes

1981 ◽  
Vol 46 (10) ◽  
pp. 2345-2353 ◽  
Author(s):  
Karel Baše ◽  
Bohumil Štíbr ◽  
Jiří Dolanský ◽  
Josef Duben
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Nmr Spectra ◽  
Liquid Ammonia ◽  
X Ray Diffraction ◽  
X Ray ◽  
H Nmr ◽  
Starting Compound

The 6-N(CH3)3-6-CB9H11 carbaborane reacts with sodium in liquid ammonia with the formation of 6-CB9H12- which was used as a starting compound for preparing the 4-CB8H14, 9-L-6-CB9H13 (L = (CH3)2S, CH3CN and P(C6H5)3), 1-(η5-C5H5)-1,2-FeCB9H10-, and 2,3-(η5-C5H5)2-2,31-Co2CB9H10- carboranes. The 4-CB8H14 compound was dehydrogenated at 623 K to give 4-(7)-CB8H12 carborane. Base degradation of 6-N(CH3)3-6-CB9H11 in methanol resulted in the formation of 3,4-μ-N(CH3)3CH-B5H10. The structure of all compounds was proposed on the basis of their 11B and 1H NMR spectra and X-ray diffraction was used in the case of the transition metal complexes.

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