Dipole moments and molecular spectra of certain derivatives of dibenzalacetone

1969 ◽  
Vol 18 (7) ◽  
pp. 1377-1380
Author(s):  
B. A. Arbuzov ◽  
L. K. Yuldasheva ◽  
I. V. Anonimova ◽  
R. R. Shagidullin ◽  
A. V. Chernova ◽  
...  
Keyword(s):  
Dipole Moments ◽  
Molecular Spectra ◽  
Derivatives Of

Use of dipole moments to determine the structure of halogen derivatives of ortho-and meta-carboranes

1968 ◽  
Vol 8 (5) ◽  
pp. 829-832
Author(s):  
V. I. Stanko ◽  
A. I. Echeistova ◽  
I. S. Astakhova ◽  
A. I. Klimova ◽  
Yu. T. Struchkov ◽  
...  
Keyword(s):  
Dipole Moments ◽  
Derivatives Of

Dipole moments and structure of derivatives of phenyl benzoate

1975 ◽  
Vol 24 (4) ◽  
pp. 701-704
Author(s):  
Yu. V. Kolodyazhnyi ◽  
V. A. Vasnev ◽  
I. A. Lapin ◽  
G. A. Alieva ◽  
M. G. Keshelava ◽  
...  
Keyword(s):  
Dipole Moments ◽  
Phenyl Benzoate ◽  
Derivatives Of

ChemInform Abstract: DIPOLE MOMENTS OF SOME N-PHENYL-SUBSTITUTED DERIVATIVES OF PYRROLIDINE, PIPERIDINE, MORPHOLINE, AND THIOMORPHOLINE

1984 ◽  
Vol 15 (22) ◽  
Author(s):  
S. F. BEACH ◽  
J. D. HEPWORTH ◽  
J. SAWYER ◽  
G. HALLAS ◽  
R. MARSDEN ◽  
...  
Keyword(s):  
Dipole Moments ◽  
Derivatives Of

Thio derivatives of b-diketones and their metal chelates. XXII. Dipole moments of some bivalent and trivalent metal complexes of fluorinated monothio-b-diketones

1976 ◽  
Vol 29 (4) ◽  
pp. 767 ◽  
Author(s):  
M Das ◽  
SE Livingstone ◽  
JH Mayfield ◽  
DS Moore ◽  
N Saha
Keyword(s):  
Copper Complexes ◽  
Dipole Moments ◽  
Platinum Complexes ◽  
Mean Value ◽  
Tetrahedral Configuration ◽  
Square Planar ◽  
Palladium And Platinum Complexes ◽  
Static Polarization ◽  
The Moment ◽  
Derivatives Of

Dipole moments have been determined by static polarization measurements for some iron(111), ruthenium(111), rhodium(111), nickel(11), palladium(11), platinum(11), copper(11) and zinc(11) complexes of fluorinated monothio-β-diketones RC(SH)=CHCOCF3. The moments indicate a facial-octahedral configuration for the iron, ruthenium and rhodium complexes, a cis-square-planar configuration for the nickel, palladium and platinum complexes, and a tetrahedral configuration for the zinc complexes. The copper complexes have moments 0.5-1.0 D lower than the mean value for the corresponding nickel, palladium and platinum complexes; this lowering of the moment is attributed to significant distortion from the square-planar towards the tetrahedral configuration. The dipole moments of the square-planar and octahedral complexes decrease if the R groups are arranged in the order: p-MeC6H4 ≥ 2-thienyl > β-naphthyl > m-MeC6H4 > Ph > Pr? > Bui > Me > m-ClC6H4 > m-BrC6H4 > p-FC6H4 > p-ClC6H4 > p-BrC6H4 > m,p-Cl2C6H3.

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