Acidity functions of solutions of propylene in aqueous sulfuric acid

Author(s):  
S. G. Entelis ◽  
G. V. Korovina ◽  
N. M. Chirkov
2021 ◽  
Vol 14 (03) ◽  
Author(s):  
A. Ramakrishna Reddy ◽  
J. Prasad ◽  
M. Bhooshan ◽  
K. C. Rajanna ◽  
A. Panasa Reddy ◽  
...  

1979 ◽  
Vol 32 (1) ◽  
pp. 41 ◽  
Author(s):  
S Yamamoto ◽  
Y Tenno ◽  
N Nishimura

Acidity functions based upon primary anilines which have no ortho substituents have been established in 20% ethanol-80% aqueous sulfuric acid solutions, and compared with those based upon o-substituted anilines and azobenzenes. It was found that the tautomeric equilibrium between azonium and anilinium forms in 4-aminoazobenzene derivatives invariably shifts to the azonium form with increase in acidity. This observation has been interpreted in terms of acidity functions.


1969 ◽  
Vol 47 (7) ◽  
pp. 1117-1122 ◽  
Author(s):  
J. T. Edward ◽  
J. K. Liu

The acid and base dissociation constants of 5,5-pentamethylene-4-thiohydantoin, 5,5-pentamethylene-2,4-dithiohydantoin, and their 1-methyl derivatives, have been determined by ultraviolet studies in basic and acid media. In aqueous sulfuric acid the 4-thiohydantoins are protonated on oxygen at the 2-position, so that the extent of protonation varies with the HA function of the acid solution, while the 2,4-dithiohydantoins are protonated on sulfur at the 2-position, so that the extent of their protonation varies with H0′′′. The importance of using acidity functions appropriate to the different types of compounds when comparing their basicities is emphasized.


2005 ◽  
Vol 152 (7) ◽  
pp. E212 ◽  
Author(s):  
Daniel R. Merrill ◽  
Ionel C. Stefan ◽  
Daniel A. Scherson ◽  
J. Thomas Mortimer

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