Thermodynamic and kinetic acidity of the CH bonds of certain ortho- and meta-barenes

1969 ◽  
Vol 18 (8) ◽  
pp. 1576-1582 ◽  
Author(s):  
�. S. Petrov ◽  
E. A. Yakovleva ◽  
G. G. Isaeva ◽  
V. N. Kalinin ◽  
L. I. Zakharkin ◽  
...  
Keyword(s):  
Kinetic Acidity

Solvolysis kinetics and mechanism of substituted 3-acetyl-1,3-diphenyltriazenes in acid medium; Kinetic acidity function

1987 ◽  
Vol 52 (9) ◽  
pp. 2212-2216
Author(s):  
Oldřich Pytela ◽  
Martin Kaska ◽  
Miroslav Ludwig ◽  
Miroslav Večeřa
Keyword(s):  
Acid Medium ◽  
Sulphuric Acid ◽  
Rate Constants ◽  
Decomposition Kinetics ◽  
Acidity Function ◽  
Hammett Equation ◽  
Kinetic Acidity ◽  
Reaction Constant ◽  
Acid Catalyzed ◽  
Catalytic Rate

The decomposition kinetics has been measured of fourteen 3-acetyl-1,3-bis(subst. phenyl)triazenes in 40% (v/v) ethanol and sulphuric acid. The kinetic acidity function and catalytic rate constants have been determined from the rate constants observed. Mechanism has been suggested for the general acid-catalyzed solvolysis from comparison of the course of the kinetic acidity function and H0 function and from the reaction constant of the Hammett equation.

Acidity of hydrocarbons. XLV. Kinetic acidity of ethylene towards cesium cyclohexylamide

1972 ◽  
Vol 13 (17) ◽  
pp. 1625-1628 ◽  
Author(s):  
M.J. Maskornick ◽  
A. Streitwieser
Keyword(s):  
Kinetic Acidity

ESR study of kinetic acidity of 6-tert-butyl-2-hydroxy-4-triphenylmethylphenoxyl

1993 ◽  
Vol 42 (1) ◽  
pp. 71-74 ◽  
Author(s):  
A. S. Masalimov ◽  
L. E. Melbardis ◽  
A. I. Prokof'ev
Keyword(s):  
Tert Butyl ◽  
Kinetic Acidity

Kinetic acidity of cubane

1991 ◽  
Vol 113 (1) ◽  
pp. 357-358 ◽  
Author(s):  
Richard E. Dixon ◽  
Andrew Streitwieser ◽  
Philip G. Williams ◽  
Philip E. Eaton
Keyword(s):  
Kinetic Acidity

Kinetic acidity function Hc.thermod.. 2. The scale in perchloric acid

1979 ◽  
Vol 44 (5) ◽  
pp. 753-757 ◽  
Author(s):  
C. David Johnson ◽  
Shaaron Rose ◽  
Peter G. Taylor
Keyword(s):  
Perchloric Acid ◽  
Acidity Function ◽  
Kinetic Acidity

Anomeric effect on kinetic acidity: Examples for the oxygen atom of ethers to accelerate abstraction of an α-hydrogen atom

1993 ◽  
Vol 34 (21) ◽  
pp. 3429-3432 ◽  
Author(s):  
Tohru Sakakibara ◽  
Shinji Ito ◽  
Hiroshi Ikegawa ◽  
Ichiro Matsuo ◽  
Akinori Seta
Keyword(s):  
Hydrogen Atom ◽  
Oxygen Atom ◽  
Anomeric Effect ◽  
Kinetic Acidity
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