X-ray spectral and Mossbauer investigations of structure defects and the degree of inversion of manganese-zinc ferrites

1982 ◽  
Vol 25 (3) ◽  
pp. 200-203
Author(s):  
P. P. Kirichok ◽  
V. P. Pashchenko ◽  
V. I. Kompaniets ◽  
G. T. Brovkina
2008 ◽  
Vol 2008 ◽  
pp. 1-7 ◽  
Author(s):  
R. L. Dhiman ◽  
S. P. Taneja ◽  
V. R. Reddy

Nanoparticles of aluminum-substituted manganese zinc ferrites,Mn1.05Zn0.05AlxFe1.9−xO4with0.4≤x≤1.0were synthesized by solid-state reaction route and characterized by XRD, TEM, and Mössbauer spectroscopy measurements. The particle size is found to very from 46 to 28 nm with increase of aluminum ions concentration. The unit cell parameter “aO” is found to decrease linearly with aluminum ions concentration due to smaller ionic radius of aluminum. The cation distributions were estimated from X-ray diffraction intensities of various planes. The theoretical lattice parameter, bulk density, porosity, X-ray density, oxygen positional parameter, ionic radii, jump length, as well as bonds and edges lengths of the tetrahedral (A-) and octahedral (B-) sites were determined.Fe57Mössbauer spectra recorded at room temperature were fitted with two sextets corresponding toFe3+ions at tetrahedral (A-) and octahedral (B-) sites. The magnetic hyperfine fields at A- and B-sites show a gradual decrease with increase ofAl3+ion concentration, which has been explained on the basis of supertransferred hyperfine field. The cation distribution obtained from X-ray intensities and Mössbauer data indicates a decrease inFe3+(B)/Fe3+(A)ratio with increasing aluminum concentration thereby suggesting a decrease in ferrimagnetic behavior.


1961 ◽  
Vol 16 (8) ◽  
pp. 1641-1641 ◽  
Author(s):  
Tsuneo Akashi ◽  
Takashi Okada

1998 ◽  
Vol 23 (0) ◽  
pp. 09-16
Author(s):  
Marco Aurélio da Silva CARVALHO FILHO ◽  
Massao IONASHIRO

Compounds of cinnamic acid with manganese, zinc and lead have been prepared in aqueous solution. Thermogravimetry, derivative thermogravimetry (TG, DTG), differential scanning calorimetry (DSC), X-ray diffraction and complexometry have been used in the characterization as well as in the study of the thermal stability and interpretation concerning the thermal decomposition.


1998 ◽  
Vol 08 (PR2) ◽  
pp. Pr2-457-Pr2-460
Author(s):  
J. Dreikorn ◽  
R. Dreyer ◽  
L. Michalowsky ◽  
J. Rossel ◽  
U. Sicker

1984 ◽  
Vol 32 (10) ◽  
pp. 1719-1729 ◽  
Author(s):  
K. Tanaka ◽  
Y. Kitahara ◽  
Y. Ichinose ◽  
T. Iimura

1979 ◽  
Vol 15 (6) ◽  
pp. 1855-1857 ◽  
Author(s):  
H. Tsunekawa ◽  
A. Nakata ◽  
T. Kamijo ◽  
K. Okutani ◽  
R. Mishra ◽  
...  

1985 ◽  
Vol 24 (4) ◽  
pp. 304-307 ◽  
Author(s):  
V. P. Pashchenko ◽  
G. T. Brovkina ◽  
V. V. Klimov ◽  
G. F. Afonina ◽  
L. N. Sharanevich

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