Rheology of filled polymers. Steady-state shear flow and periodic deformation. 1. Relaxation time spectra, viscosity

1978 ◽  
Vol 13 (6) ◽  
pp. 898-906 ◽  
Author(s):  
L. A. Faitel'son ◽  
�. �. Yakobson
Keyword(s):  
Relaxation Time ◽  
Steady State ◽  
Shear Flow ◽  
Filled Polymers ◽  
Periodic Deformation

Numerical study of electric field effects on the deformation of two-dimensional liquid drops in simple shear flow at arbitrary Reynolds number

2009 ◽  
Vol 626 ◽  
pp. 367-393 ◽  
Author(s):  
STEFAN MÄHLMANN ◽  
DEMETRIOS T. PAPAGEORGIOU
Keyword(s):  
Steady State ◽  
Shear Flow ◽  
Electric Field ◽  
Electric Fields ◽  
Simple Shear ◽  
Simple Shear Flow ◽  
Physical Parameters ◽  
Shear Stresses ◽  
Two Dimensional ◽  
Liquid Drops

The effect of an electric field on a periodic array of two-dimensional liquid drops suspended in simple shear flow is studied numerically. The shear is produced by moving the parallel walls of the channel containing the fluids at equal speeds but in opposite directions and an electric field is generated by imposing a constant voltage difference across the channel walls. The level set method is adapted to electrohydrodynamics problems that include a background flow in order to compute the effects of permittivity and conductivity differences between the two phases on the dynamics and drop configurations. The electric field introduces additional interfacial stresses at the drop interface and we perform extensive computations to assess the combined effects of electric fields, surface tension and inertia. Our computations for perfect dielectric systems indicate that the electric field increases the drop deformation to generate elongated drops at steady state, and at the same time alters the drop orientation by increasing alignment with the vertical, which is the direction of the underlying electric field. These phenomena are observed for a range of values of Reynolds and capillary numbers. Computations using the leaky dielectric model also indicate that for certain combinations of electric properties the drop can undergo enhanced alignment with the vertical or the horizontal, as compared to perfect dielectric systems. For cases of enhanced elongation and alignment with the vertical, the flow positions the droplets closer to the channel walls where they cause larger wall shear stresses. We also establish that a sufficiently strong electric field can be used to destabilize the flow in the sense that steady-state droplets that can exist in its absence for a set of physical parameters, become increasingly and indefinitely elongated until additional mechanisms can lead to rupture. It is suggested that electric fields can be used to enhance such phenomena.

scholarly journals Anisotropic clustering of inertial particles in homogeneous shear flow

2009 ◽  
Vol 629 ◽  
pp. 25-39 ◽  
Author(s):  
P. GUALTIERI ◽  
F. PICANO ◽  
C. M. CASCIOLA
Keyword(s):  
Relaxation Time ◽  
Shear Flow ◽  
Large Scale ◽  
Inertial Particles ◽  
Spatial Homogeneity ◽  
Homogeneous Shear ◽  
Multi Scale ◽  
Angular Distribution Function ◽  
Homogeneous Shear Flow ◽  
Anisotropic Clustering

Recently, clustering of inertial particles in turbulence has been thoroughly analysed for statistically homogeneous isotropic flows. Phenomenologically, spatial homogeneity of particle configurations is broken by the advection of a range of eddies determined by the Stokes relaxation time of the particles. This in turn results in a multi-scale distribution of local particle concentration and voids. Much less is known concerning anisotropic flows. Here, by addressing direct numerical simulations (DNS) of a statistically steady particle-laden homogeneous shear flow, we provide evidence that the mean shear preferentially orients particle patterns. By imprinting anisotropy on large-scale velocity fluctuations, the shear indirectly affects the geometry of the clusters. Quantitative evaluation is provided by a purposely designed tool, the angular distribution function (ADF) of particle pairs, which allows to address the anisotropy content of particle aggregates on a scale-by-scale basis. The data provide evidence that, depending on the Stokes relaxation time of the particles, anisotropic clustering may occur even in the range of scales in which the carrier phase velocity field is already recovering isotropy. The strength of the singularity in the anisotropic component of the ADF quantifies the level of fine-scale anisotropy, which may even reach values of more than 30% direction-dependent variation in the probability to find two closeby particles at viscous-scale separation.

Elastic recovery of immiscible blends 1. Analysis after steady state shear flow

1999 ◽  
Vol 38 (1) ◽  
pp. 65-72 ◽  
Author(s):  
I. Vinckier ◽  
P. Moldenaers ◽  
J. Mewis
Keyword(s):  
Steady State ◽  
Shear Flow ◽  
Elastic Recovery ◽  
Immiscible Blends

scholarly journals Studies on dielectric relaxation in relation to viscosity of some anilines, phenol, and their binary mixtures at microwave frequencies

2019 ◽  
Vol 97 (2) ◽  
pp. 210-215
Author(s):  
C.V. Maridevarmath ◽  
G.H. Malimath
Keyword(s):  
Relaxation Time ◽  
Steady State ◽  
Dynamic Viscosity ◽  
Room Temperature ◽  
Viscoelastic Model ◽  
Frictional Resistance ◽  
Nonlinear Behaviour ◽  
Viscoelastic Relaxation ◽  
Microwave Frequencies ◽  
Loss Formula

In the present work, the study of variation of relaxation time (τ) with viscosity of the medium (η) is carried out on four polar samples: 2-Nitroaniline, 4-Bromoaniline, 4-Chloroaniline, 4-Chlorophenol, and also on the binary mixture of 2-Nitroaniline + 4-Bromoaniline at room temperature by using microwave bench operating at a frequency of 9.59 GHz. In this regard, the different parameters like dielectric constant ([Formula: see text]), dielectric loss ([Formula: see text]), relaxation time (τs), macroscopic steady state viscosity (ηs), dynamic viscosity (ηd), and viscoelastic relaxation time (τve) were determined for all the systems. It is observed that the relaxation time (τs) increases with the increase in the viscosity of the medium for all the systems. Plots of log(τs) versus log(ηs) for all the systems show that variation of relaxation time is found to be nonlinear in the higher viscosity regions. This suggests the failure of Debye’s theory at these regions. Further, the nonlinear behaviour of relaxation time with the viscosity is explained by using the viscoelastic model suggested by Barlow et al. (Proc. R. Soc. A 309, 473 (1969). doi: 10.1098/rspa.1969.0053 ). It is also observed that macroscopic steady state viscosity (ηs) values are greater than the dynamic viscosity (ηd), and viscoelastic relaxation time (τve) values were found to be lower compared to the relaxation time (τs). These results suggest that the effective frictional resistance experienced by the molecules during reorientation is lower and the measured values of macroscopic steady state viscosity (ηs) are frequency dependent.

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