Metalation of barene and its derivatives with alkali metal amides in liquid ammonia

1965 ◽  
Vol 14 (1) ◽  
pp. 138-140
Author(s):  
L. I. Zakharkin
Keyword(s):  
Alkali Metal ◽  
Liquid Ammonia ◽  
Metal Amides

ChemInform Abstract: FORMATION OF OXAZOLINES BY REACTION OF ALKALI METAL AMIDES WITH α-CHLORINATED KETONES IN LIQUID AMMONIA

1976 ◽  
Vol 7 (25) ◽  
pp. no-no
Author(s):  
MARCEL MIOCQUE ◽  
CLAUDE COMBET-FARNOUX ◽  
JEAN-FRANCOIS GIRARDEAU ◽  
HERVE GALONS
Keyword(s):  
Alkali Metal ◽  
Liquid Ammonia ◽  
Metal Amides

Compounds of the triphenyltin(II) ion

1981 ◽  
Vol 34 (6) ◽  
pp. 1337 ◽  
Author(s):  
WR Bullard ◽  
MJ Taylor
Keyword(s):  
Alkali Metal ◽  
Vibrational Spectra ◽  
Liquid Ammonia ◽  
Crystalline Solids ◽  
Ionic Compounds ◽  
Metal Derivatives

Ionic compounds R+SnPh3-, where R = Me4N, (Ph3P)2N, Na(15-crown-5) or K(18-crown-6), are prepared from alkali metal derivatives, Ph3SnM, by reactions in liquid ammonia which yield the products as yellow crystalline solids, soluble in a weakly basic solvent. N.m.r. and vibrational spectra of the Ph3Sn- anion, a pyramidal species with C3V symmetry, and the cationic complexes [M(crown)]+, are reported and assigned.

scholarly journals Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali‐Metal Amides under Air

2020 ◽  
Vol 59 (43) ◽  
pp. 19021-19026 ◽  
Author(s):  
Florian F. Mulks ◽  
Leonie J. Bole ◽  
Laia Davin ◽  
Alberto Hernán‐Gómez ◽  
Alan Kennedy ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Metal Amides

Synthesis and Structures of Alkali Metal Amides Derived from the Ligands [N(SiMe2Ph)(SiMe3)]−, [N(tBu)(SiMe3)]−, [N(Ph)(2-C5H4N)]−, and [N(2-C5H4N)2]−

2003 ◽  
Vol 2003 (18) ◽  
pp. 3391-3400 ◽  
Author(s):  
Floria Antolini ◽  
Peter B. Hitchcock ◽  
Alexei V. Khvostov ◽  
Michael F. Lappert
Keyword(s):  
Alkali Metal ◽  
Metal Amides

Titanium Carbene Complexes Stabilized by Alkali Metal Amides

2019 ◽  
Vol 58 (6) ◽  
pp. 1833-1837 ◽  
Author(s):  
Hassan Osseili ◽  
Khai‐Nghi Truong ◽  
Thomas P. Spaniol ◽  
Laurent Maron ◽  
Ulli Englert ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Carbene Complexes ◽  
Metal Amides

Enhancement of the initial hydrogenation of Mg by ball milling with alkali metal amides MNH2(M = Li or Na)

2015 ◽  
Vol 44 (38) ◽  
pp. 16694-16697 ◽  
Author(s):  
Hailiang Chu ◽  
Shujun Qiu ◽  
Lixian Sun ◽  
Jacques Huot
Keyword(s):  
Alkali Metal ◽  
Ball Milling ◽  
Metal Amides

The addition of 4 wt% of MNH2(M = Li, Na) to pure Mg by ball milling greatly enhances the first hydrogenation (activation). Under 2 MPa of H2at 608 K, the best activation performance was achieved with the NaNH2additive.

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