Nitrosyl derivatives of molybdenum pentachloride and tungsten hexachloride

1972 ◽  
Vol 21 (4) ◽  
pp. 905-907 ◽  
Author(s):  
Yu. A. Buslaev ◽  
N. A. Ovchinnikova ◽  
M. M. Ershova ◽  
M. A. Glushkova
Keyword(s):  
Molybdenum Pentachloride ◽  
Tungsten Hexachloride ◽  
Derivatives Of ◽  
And Tungsten

Carbonyl halides of the Group VI transition metals. XI. Dithiocyanatocarbonyl derivatives of molybdenum and tungsten(II)

1968 ◽  
Vol 21 (6) ◽  
pp. 1435 ◽  
Author(s):  
R Colton ◽  
GR Scollary
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Ammonium Chloride ◽  
Pure State ◽  
Ammonium Thiocyanate ◽  
Donor Ligands ◽  
Group Vi ◽  
Derivatives Of ◽  
And Tungsten

Reaction of ammonium thiocyanate with dihalocarbonyls of molybdenum and tungsten(11) leads to the elimination of ammonium chloride and the formation of a dithiocyanatocarbonyl complex of the transition metal. Although the thiocyanatocarbonyls themselves have not been isolated in a pure state, a number of substituted derivatives with phosphorus donor ligands have been prepared and characterized. In general these complexes are less stable than the corresponding carbonyl halide derivatives.

scholarly journals Synthesis of new half sandwich tetrachloro derivatives of molybdenum(V) and tungsten(V). X-ray structures of (C5HPri4)W(CO)3(CH3) and (C5Et5)WCl4

2002 ◽  
Vol 654 (1-2) ◽  
pp. 109-116 ◽  
Author(s):  
Matthias Bastian ◽  
Dolores Morales ◽  
Rinaldo Poli ◽  
Philippe Richard ◽  
Helmut Sitzmann
Keyword(s):  
X Ray ◽  
Derivatives Of ◽  
Half Sandwich ◽  
And Tungsten
Sign in / Sign up

Export Citation Format

Share Document