Thermal decomposition of 2,6-di-tert-butyl-p-benzoquinone diazide in cyclic ethers

1972 ◽  
Vol 21 (8) ◽  
pp. 1757-1760
Author(s):  
G. A. Nikiforov ◽  
L. G. Plekhanova ◽  
V. V. Ershov
Keyword(s):  
Thermal Decomposition ◽  
Cyclic Ethers ◽  
Tert Butyl

Thermal decomposition of trimethylsilyl tert-butyl persuccinate

1981 ◽  
Vol 30 (12) ◽  
pp. 2333-2336
Author(s):  
G. A. Razuvaev ◽  
G. V. Basova ◽  
O. S. D′yachkovskaya ◽  
V. A. Dodonov ◽  
S. V. Krasnodubskaya
Keyword(s):  
Thermal Decomposition ◽  
Tert Butyl

Tri(tert-butyl)phosphinoxid, -imin, -methylen und -boran / Tri(tert-butyl)phosphine Oxide, Imine, Methylene and Borane

1978 ◽  
Vol 33 (12) ◽  
pp. 1556-1558 ◽  
Author(s):  
Hubert Schmidbaur ◽  
Günter Blaschke
Keyword(s):  
Thermal Decomposition ◽  
Phosphine Oxide ◽  
Steric Hindrance ◽  
Reductive Elimination ◽  
Tert Butyl

Abstract Tri(tert-butyl)phosphine Oxide, Imine, Methylene, Borane Tri(tert-butyl)phosphine oxide, imine, methylene and borane have been prepared and their properties investigated. The imine is chemically inert due to strong steric hindrance. Its thermal decomposition at 200 °C leads to tri(tert-butyl)-pliosphine, in contrast to the methylene analogue which undergoes reductive elimination of isobutene. Both the oxide and borane are thermally very stable (> 250 °C).

Effect of ionic liquids on the thermal decomposition process of tert-butyl peroxybenzoate (TBPB) by DSC

2019 ◽  
Vol 671 ◽  
pp. 127-133 ◽  
Author(s):  
Jun-Cheng Jiang ◽  
Li Li ◽  
Jia-Jia Jiang ◽  
Yan Wang ◽  
Siu-Ming Lo ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Ionic Liquids ◽  
Decomposition Process ◽  
Thermal Decomposition Process ◽  
Tert Butyl

ChemInform Abstract: GAS PHASE THERMAL DECOMPOSITION OF TERT.-BUTYL ALCOHOL

1974 ◽  
Vol 5 (38) ◽  
pp. no-no
Author(s):  
DAVID LEWIS ◽  
MARK KEIL ◽  
MICHAEL SARR
Keyword(s):  
Thermal Decomposition ◽  
Gas Phase ◽  
Butyl Alcohol ◽  
Tert Butyl ◽  
Tert Butyl Alcohol

THE DECOMPOSITION OF SILYL PEROXIDES

1964 ◽  
Vol 42 (5) ◽  
pp. 985-989 ◽  
Author(s):  
Richard R. Hiatt
Keyword(s):  
Thermal Decomposition ◽  
Rate Constant ◽  
Half Life ◽  
Order Rate Constant ◽  
Butyl Alcohol ◽  
Base Catalysis ◽  
First Order ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Acid And Base

The thermal decomposition of tert-butyl trimethylsilyl peroxide has been investigated and found to be sensitive to acid and base catalysis and to the nature of the solvent. In heptane and iso-octane the first-order rate constant could be expressed as 1.09 × 1015e−41200/RT and in 1-octene as 3.90 × 1015e−41200/RT (sec−1). The half life at 203 °C was about 1 hour. The reaction was faster in aromatic solvents; in chlorobenzene it was complicated by formation of HCl from the solvent.Products of the reaction were acetone, tert-butyl alcohol and hexamethyldisiloxane.

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