Problems of the structure of aqueous solutions of electrolytes

1973 ◽  
Vol 22 (2) ◽  
pp. 277-281 ◽  
Author(s):  
A. K. Lyashchenko
Keyword(s):  
Aqueous Solutions ◽  
Solutions Of Electrolytes ◽  
Structure Of Aqueous Solutions

Gas holdup in bubbled beds of aqueous solutions of electrolytes

1977 ◽  
Vol 42 (9) ◽  
pp. 2642-2650
Author(s):  
F. Kaštánek ◽  
J. Kratochvíl ◽  
J. Pata ◽  
M. Rylek
Keyword(s):  
Aqueous Solutions ◽  
Gas Holdup ◽  
Solutions Of Electrolytes

The metachor as a characteristic of the association of electrolytes in aqueous solutions

1984 ◽  
Vol 49 (5) ◽  
pp. 1061-1078 ◽  
Author(s):  
Jiří Čeleda ◽  
Stanislav Škramovský
Keyword(s):  
Aqueous Solutions ◽  
Apparent Volume ◽  
Solutions Of Electrolytes ◽  
Molal Volumes ◽  
The Difference ◽  
High Concentrations ◽  
Experimental Values ◽  
Suitable Characteristic ◽  
Association Of Ions ◽  
Very High

Based on the earlier paper introducing a concept of the apparent parachor of a solute in the solution, we have eliminated in the present work algebraically the effect which is introduced into this quantity by the additivity of the apparent molal volumes. The difference remaining from the apparent parachor after substracting the contribution corresponding to the apparent volume ( for which the present authors suggest the name metachor) was evaluated from the experimental values of the surface tension of aqueous solutions for a set of 1,1-, 1,2- and 2,1-valent electrolytes. This difference showed to be independent of concentration up to the very high values of the order of units mol dm-3 but it was directly proportional to the number of the free charges (with a proportionality factor 5 ± 1 cm3 mol-1 identical for all studied electrolytes). The metachor can be, for this reason, a suitable characteristic for detection of the association of ions and formation of complexes in the solutions of electrolytes, up to high concentrations where other methods are failing.

Physico-chemical study of aqueous solutions of electrolytes in mixed solvents

2006 ◽  
Vol 38 (11) ◽  
pp. 1474-1478 ◽  
Author(s):  
Monimul Huque ◽  
Iqbal Ahmed Siddiquey ◽  
Md. Nizam Uddin
Keyword(s):  
Aqueous Solutions ◽  
Mixed Solvents ◽  
Chemical Study ◽  
Physico Chemical ◽  
Solutions Of Electrolytes
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