A single structural type in the series of oxyorthosilicates of the rare earth elements

Author(s):  
Yu. I. Smolin ◽  
Yu. F. Shepelev ◽  
I. A. Bondar' ◽  
N. A. Toropov
2021 ◽  
Vol 63 (2) ◽  
pp. 255
Author(s):  
Н.И. Сорокин

The effect of strong deviations from stoichiometry in the structural type of fluorite (CaF2) on the microhardness of Ba0.9R0.1F2.1 crystals (R is the rare earth elements La-Lu) has been studied. Mechanical hardening of heterovalent Ba0.9R0.1F2.1 solid solutions in comparison with the BaF2 matrix is due to the formation of nanosized clusters of point defects [Ba8R6F69], replacing structural fragments [Ba14F64] (block type of isomorphism). It was found that, with a decrease in the cluster size from [Ba8La6F69] to [Ba8Lu6F69], the microhardness of nanostructured Ba0.9R0.1F2.1 crystals increases by 73%.


1962 ◽  
Vol 18 (4) ◽  
pp. 1127-1153
Author(s):  
V FASSEL ◽  
R CURRY ◽  
R KNISELEY

2017 ◽  
Vol 8 (1) ◽  
Author(s):  
Takaaki Hatanaka ◽  
Akimasa Matsugami ◽  
Takamasa Nonaka ◽  
Hideki Takagi ◽  
Fumiaki Hayashi ◽  
...  

1967 ◽  
Vol 22 (4) ◽  
pp. 551-555 ◽  
Author(s):  
W. Jeitschko ◽  
E. Parthé

1962 ◽  
Vol 18 (9) ◽  
pp. 1127-1153 ◽  
Author(s):  
V.A. Fassel ◽  
R.H. Curry ◽  
R.N. Kniseley

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