The equation of state and thermodynamic properties of molecular nitrogen

1965 ◽  
Vol 8 (1) ◽  
pp. 24-28 ◽  
Author(s):  
P. M. Kessel'man ◽  
P. A. Kotlyarevskii ◽  
A. P. Voloshin
Keyword(s):  
Equation Of State ◽  
Thermodynamic Properties ◽  
Molecular Nitrogen

A Rational Equation of State for Water and Water Vapor in the Critical Region

1964 ◽  
Vol 86 (3) ◽  
pp. 320-326 ◽  
Author(s):  
E. S. Nowak
Keyword(s):  
Water Vapor ◽  
Equation Of State ◽  
Thermodynamic Properties ◽  
Specific Heat ◽  
Critical Point ◽  
Critical Region ◽  
Constant Pressure ◽  
Parametric Equation ◽  
Enthalpy And Entropy ◽  
Specific Volumes

A parametric equation of state was derived for water and water vapor in the critical region from experimental P-V-T data. It is valid in that part of the critical region encompassed by pressures from 3000 to 4000 psia, specific volumes from 0.0400 to 0.1100 ft3/lb, and temperatures from 698 to 752 deg F. The equation of state satisfies all of the known conditions at the critical point. It also satisfies the conditions along certain of the boundaries which probably separate “supercritical liquid” from “supercritical vapor.” The equation of state, though quite simple in form, is probably superior to any equation heretofore derived for water and water vapor in the critical region. Specifically, the deviations between the measured and computed values of pressure in the large majority of the cases were within three parts in one thousand. This coincides approximately with the overall uncertainty in P-V-T measurements. In view of these factors, the author recommends that the equation be used to derive values for such thermodynamic properties as specific heat at constant pressure, enthalpy, and entropy in the critical region.

Thermodynamic properties of liquid mixtures: Selection of the pure liquid parameter

1974 ◽  
Vol 27 (3) ◽  
pp. 647 ◽  
Author(s):  
DV Fenby ◽  
NF Pasco
Keyword(s):  
Equation Of State ◽  
Thermodynamic Properties ◽  
Equations Of State ◽  
Liquid Mixtures ◽  
Pure Liquid ◽  
Excess Thermodynamic Properties ◽  
Pure Fluids ◽  
Liquid Parameter ◽  
Selection Of

There has recently been a revival of interest in theories of liquid mixtures based on analytic equations of state for pure fluids. We have shown that the method used to determine the parameters of the pure-liquid equation of state has a significant effect on the excess thermodynamic properties obtained from such theories.

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