Kinetics of oxidation of ethyldigol by vanadium(V) in aqueous acidic medium

1987 ◽  
Vol 118 (1) ◽  
pp. 63-70 ◽  
Author(s):  
Narendra Nath ◽  
R. C. Dubey ◽  
U. S. Misra
Keyword(s):  
Acidic Medium ◽  
Kinetics Of Oxidation ◽  
Kinetics Of ◽  
Aqueous Acidic Medium

scholarly journals Kinetics and Mechanism of Oxidation of Glutamic Acid byN-Bromophthalimide in Aqueous Acidic Medium

2011 ◽  
Vol 8 (4) ◽  
pp. 1472-1477
Author(s):  
N. M. I. Alhaji ◽  
S. Sofiya Lawrence Mary
Keyword(s):  
Dielectric Constant ◽  
Ionic Strength ◽  
Glutamic Acid ◽  
Acidic Medium ◽  
Reaction Medium ◽  
Kinetics Of Oxidation ◽  
First Order ◽  
Mechanism Of Oxidation ◽  
Kinetics Of ◽  
Aqueous Acidic Medium

The kinetics of oxidation of glutamic acid (Glu) withN-bromophthalimide (NBP) was studied in perchloric acid medium at 30°C by potentiometric method. The reaction is first order each in NBP and glutamic acid and is negative fractional order in [H+]. Addition of KBr or the reaction product, phthalimide had no effect on the rate. Similarly variation of ionic strength of the medium did not affect the rate of the reaction. Also the rate increased with decrease in dielectric constant of the reaction medium. The thermodynamic parameters were computed from Arrhenius and Eyring plots. A suitable mechanism consistent with the kinetic results has been proposed.

scholarly journals Kinetics and Mechanism of the Oxidation of Naphthol Green B by Peroxydisulphate Ion in Aqueous Acidic Medium

2014 ◽  
Vol 2014 ◽  
pp. 1-4
Author(s):  
B. Myek ◽  
S. O. Idris ◽  
J. F. Iyun
Keyword(s):  
Acidic Medium ◽  
Reaction Medium ◽  
Intermediate Complex ◽  
Kinetic Investigation ◽  
Hydrogen Ions ◽  
First Order ◽  
Order Dependence ◽  
Naphthol Green B ◽  
Kinetics Of ◽  
Aqueous Acidic Medium

The kinetics of the oxidation of naphthol green B (NGB3−) by peroxydisulphate ion has been carried out in aqueous acidic medium at λmax of 700 nm, T=23±1°C, and I=0.50 mol dm−3 (NaCl). The reaction shows a first-order dependence on oxidant and reductant concentration, respectively. The stoichiometry of the NGB—S2O82- reaction is 1 : 2. Change in hydrogen ions concentration of the reaction medium has no effect on the rate of the reaction. Added cations and anions decreased the rate of the reaction. The results of spectroscopic and kinetic investigation indicate that no intermediate complex is probably formed in the course of this reaction.

Kinetics of iridium(III) catalyzed oxidation of benzaldehyde and p-nitrobenzaldehyde by cerium(IV) in aqueous acidic medium

2008 ◽  
Vol 33 (6) ◽  
pp. 791-795 ◽  
Author(s):  
Praveen K. Tandon ◽  
Manisha Purwar ◽  
Priy B. Dwivedi ◽  
Manish Srivastava
Keyword(s):  
Acidic Medium ◽  
Kinetics Of ◽  
Catalyzed Oxidation ◽  
Aqueous Acidic Medium

Kinetics and mechanism of the oxidation of 1-propane thiol by 2,6-dichlorophenolindophenol in acidic medium

1982 ◽  
Vol 60 (15) ◽  
pp. 1928-1932 ◽  
Author(s):  
M. Kashyap ◽  
K. K. Mishra ◽  
N. K. Pandey
Keyword(s):  
Kinetic Data ◽  
Acidic Medium ◽  
Reaction System ◽  
Activation Parameters ◽  
Molar Ratio ◽  
Water Medium ◽  
Reaction Products ◽  
Kinetics Of Oxidation ◽  
Acetone Water ◽  
Kinetics Of

The kinetics of oxidation of 1-propanethiol by 2,6-dichlorophenolindophenol have been studied in acetone–water medium and in the presence of phosphate buffer. The principal reactants interact in a molar ratio of 2:1 forming disulphide and dihydroindophenol. The reaction follows second order kinetics in indophenol while the order is unity in thiol. The rate increases linearly on increasing [H+]. The rate of oxidation increases on increasing the ionic strength as well as the dielectric constant of the reaction system. The addition of reaction products has no effect on the rate. Activation parameters have been evaluated and a suitable mechanism consistent with kinetic data is suggested.

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