Electronic structure of monoligand complexes of transition metals in the X?-scattered wave approximation. I. The complexes M-N2 (M=Mn, Fe, Co, Ni, Cu)

1984 ◽  
Vol 25 (1) ◽  
pp. 5-9
Author(s):  
S. G. Gagarin ◽  
Yu. A. Tererin ◽  
I. G. Fal'kov
Keyword(s):  
Electronic Structure ◽  
Transition Metals ◽  
Scattered Wave ◽  
Wave Approximation ◽  
Complexes Of Transition Metals

MO study of Td-D4h equilibrium in complexes of transition metals. II. Equilibrium in tetrafluoro and tetrabromo complexes of atoms of the first transition row

1984 ◽  
Vol 49 (12) ◽  
pp. 2837-2856 ◽  
Author(s):  
Peter Pelikán ◽  
Marek Liška
Keyword(s):  
Electronic Structure ◽  
Transition Metals ◽  
Central Atom ◽  
Spin States ◽  
Cndo Method ◽  
Oxidation Degree ◽  
High Spin States ◽  
Square Planar ◽  
Complexes Of Transition Metals ◽  
Square Planar Complexes

The CNDO method for transition metals in the UHF version has been used to study the equilibrium of configuration isomers of tetrahedral and square-planar tetrafluoro and tetrabromo complexes of the first transition row atoms in the oxidation degree II (Mn(II), Fe(II), Co(II), Ni(II), Cu(II) both in low-spin and in high-spin states. The results show that the ability (given by electronic structure of the central atom) to form the square-planar complexes decreases monotonously in the series: Mn(II) > Fe(II) > Co(II) > Ni(II) > Cu(II). With respect to the effect of the electronic structure of ligands, the same ability decreases in the series: F- > Cl- > Br-.

ChemInform Abstract: Phosphoraneiminato Complexes of Transition Metals

ChemInform ◽  
2010 ◽  
Vol 30 (18) ◽  
pp. no-no
Author(s):  
Kurt Dehnicke ◽  
Matthias Krieger ◽  
Werner Massa
Keyword(s):  
Transition Metals ◽  
Complexes Of Transition Metals

Catalytic autooxidation of hydroquinone in the presence of chelate complexes of transition metals

1982 ◽  
Vol 21 (1-2) ◽  
pp. 41-44 ◽  
Author(s):  
M. E. Volpin ◽  
M. Jáky ◽  
E. M. Kolosova ◽  
M. Yu. Tuvin ◽  
G. N. Novodarova
Keyword(s):  
Transition Metals ◽  
Chelate Complexes ◽  
Complexes Of Transition Metals
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