Kinetics of the reduction-oxidation processes taking place during the heating of powders produced from cast iron swarf

1988 ◽  
Vol 27 (6) ◽  
pp. 411-414
Author(s):  
S. S. Kiparisov ◽  
O. V. Padalko ◽  
E. S. Bogodukhova ◽  
L. A. Pronin ◽  
A. S. Mints
2018 ◽  
Vol 69 (5) ◽  
pp. 1139-1144
Author(s):  
Iosif Lingvay ◽  
Adriana Mariana Bors ◽  
Livia Carmen Ungureanu ◽  
Valerica Stanoi ◽  
Traian Rus

For the purpose of using three different types of painting materials for the inner protection of the transformer vats, their behavior was studied under actual conditions of operation in the transformer (thermal stress in electro-insulating fluid based on the natural ester in contact with copper for electro-technical use and electro-insulating paper). By comparing determination of the content in furans products (HPLC technique) and gases formed (by gas-chromatography) in the electro-insulating fluid (natural ester with high oleic content) thermally aged at 130 �C to 1000 hours in closed glass vessels, it have been found that the presence the investigated painting materials lead to a change in the mechanism and kinetics of the thermo-oxidation processes. These changes are supported by oxygen dissolved in oil, what leads to decrease both to gases formation CO2, CO, H2, CH4, C2H4 and C2H6) and furans products (5-HMF, 2-FOL, 2 -FAL and 2-ACF). The painting materials investigated during the heat treatment applied did not suffer any remarkable structural changes affecting their functionality in the electro-insulating fluid based on vegetable esters.


Author(s):  
Zahia Benredjem ◽  
Karima Barbari ◽  
Imene Chaabna ◽  
Samia Saaidia ◽  
Abdelhak Djemel ◽  
...  

Abstract The Advanced Oxidation Processes (AOPs) are promising environmentally friendly technologies for the treatment of wastewater containing organic pollutants in general and particularly dyes. The aim of this work is to determine which of the AOP processes based on the Fenton reaction is more effective in degrading the methyl orange (MO) dye. The comparative study of the Fenton, photo-Fenton (PF) and electro-Fenton (EF) processes has shown that electro-Fenton is the most efficient method for oxidizing Methyl Orange. The evolution of organic matter degradation was followed by absorbance (discoloration) and COD (mineralization) measurements. The kinetics of the MO degradation by the electro-Fenton process is very rapid and the OM degradation rate reached 90.87% after 5 min. The influence of some parameters such as the concentration of the catalyst (Fe (II)), the concentration of MO, the current density, the nature and the concentration of supporting electrolyte was investigated. The results showed that the degradation rate increases with the increase in the applied current density and the concentration of the supporting electrolyte. The study of the concentration effect on the rate degradation revealed optimal values for the concentrations 2.10−5 M and 75 mg L−1 of Fe (II) and MO respectively.


1984 ◽  
Vol 34 ◽  
Author(s):  
P. L. Roy ◽  
A. K. Chakrabart ◽  
P. Banerjee

ABSTRACTMinor additions (0.05-0.2 wt.%) of sodium chloride, hexachloroethane and elemental sulphur to commercial white iron melts have been found to enhance the kinetics of first stage graphitisation during subsequent annealing of white iron samples. The optimum dose of sodium chloride and hexachloroethane addition is around 0.1%. Yield strength and ductility of annealed test bars treated with NaCl or C2Cl6 compare favourably with those of untreated test bars. Sulphur treatment causes slight deterioration in mechanical properties. Fully grown nodules in both treated and untreated samples appear porous under SEM. Possible mechanisms of acceleration of graphitisation in the treated samples have been suggested.


2017 ◽  
Vol 43 (17) ◽  
pp. 15708-15713 ◽  
Author(s):  
Abhinav ◽  
N. Krishnamurthy ◽  
Ranjana Jain

1977 ◽  
Vol 9 (12) ◽  
pp. 1462-1467
Author(s):  
I. S. Guz' ◽  
A. P. Lyubchenko ◽  
V. M. Matsevityi ◽  
S. L. Molodtsov ◽  
L. A. Smirnova

1970 ◽  
Vol 12 (12) ◽  
pp. 991-993
Author(s):  
G. F. Tikhonov ◽  
A. P. Rukavishnikova

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