Quaternary ammonium salts with labile $$\begin{array}{*{20}c} + \\ N \\ \end{array} - - C$$ bond as precursors of medicinal compounds. III. Alkaline hydrolysis of cyclozil chloromethacryloyloxymethylate

1983 ◽  
Vol 17 (12) ◽  
pp. 876-881
Author(s):  
S. M. Chigareva ◽  
S. G. Kuznetsov ◽  
N. D. Vinogradova
Keyword(s):  
Alkaline Hydrolysis ◽  
Quaternary Ammonium ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Medicinal Compounds ◽  
Hydrolysis Of

Alkaline Hydrolysis of Substituted Phenyl Acetates Catalyzed by Quaternary Ammonium Salts

1993 ◽  
Vol 58 (12) ◽  
pp. 2891-2895 ◽  
Author(s):  
Jiří Kulič ◽  
Jiří Sussenbek ◽  
Aleš Ptáček
Keyword(s):  
Ammonium Chloride ◽  
Alkaline Hydrolysis ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Ammonium Bromide ◽  
Hexadecyltrimethylammonium Bromide ◽  
Rate Data ◽  
Hammett Equation ◽  
Efficient Catalyst ◽  
Hydrolysis Of

Alkaline hydrolysis if the phenyl acetates CH3COOC6H4X (X = 4-NO2, 3-NO2, 3-Cl, H, 4-CH3, 3-CH3, and 4-OCH3) in the presence of hexadecyltris(2-hydroxyethyl)ammonium chloride, bis(2-hydroxyethyl)hexadecyl(methyl)ammonium bromide, and hexadecyltrimethylammonium bromide has been studied. Comparison of the rates of the hydrolysis for the above tenzides showed that the most efficient catalyst is the hexadecyltris(2-hydroxyethyl)ammonium chloride. In all cases, the rate data correlated well with structure effects by the Hammett equation.

Effect of quaternary ammonium salts on the hydrolysis of N-glutaryl-l-phenylalanine catalysed by α-chymotrypsin

2004 ◽  
Vol 28 (2-3) ◽  
pp. 101-110 ◽  
Author(s):  
Paolo Viparelli ◽  
Francesco Alfani ◽  
Alberto Gallifuoco ◽  
Maria Cantarella
Keyword(s):  
Quaternary Ammonium ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Hydrolysis Of

Synthesis and stability of 1-aminoalkylphosphonic acid quaternary ammonium salts

2021 ◽  
Author(s):  
Tomasz K. Olszewski ◽  
Anna Brol
Keyword(s):  
Phosphonic Acid ◽  
Quaternary Ammonium ◽  
Alkylating Agent ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Aminoalkylphosphonic Acid

An effective protocol for quaternization of simple 1-aminoalkylphosphonic acids under basic conditions and using Me2SO4 as convenient alkylating agent is reported. In the course of reaction phosphonic acid quaternary ammonium...

scholarly journals Green Accelerated Synthesis, Antimicrobial Activity and Seed Germination Test of Quaternary Ammonium Salts of 1,2-bis(4-pyridyl)ethane

Molecules ◽  
2019 ◽  
Vol 24 (13) ◽  
pp. 2424 ◽  
Author(s):  
Tăbăcaru ◽  
Botezatu ◽  
Horincar ◽  
Furdui ◽  
Dinică
Keyword(s):  
Escherichia Coli ◽  
Triticum Aestivum ◽  
Seed Germination ◽  
Quaternary Ammonium ◽  
Pathogenic Bacteria ◽  
Classical Method ◽  
Triticum Aestivum L ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Radicle Growth

A family of fifteen quaternary ammonium salts (QAs), bearing the 1,2-bis(4-pyridyl)ethane core, were obtained using for the first time two different green methods, such as microwave (MW) and ultrasounds (US) irradiation, with very good yields and in much shorter times compared to the classical method, and an assay on their antimicrobial action against Escherichia coli (E. coli) was carried out. While 12 to 24 hours were required for complete alkylation of 1,2-bis(4-pyridyl)ethane by reactive halogenated derivatives in anhydrous solvent under reflux conditions, MW and US irradiation reduced the reaction time and the desired products were achieved in a few min. One of the aims of this study was to evaluate the antibacterial potential of the synthesized QAs against pathogenic bacteria, along with their impact on germination activity of wheat seeds (Triticum aestivum L.). The antibacterial activity of the QAs against Escherichia coli was explored by determining the minimum inhibitory concentration (MIC). The MIC values varied from 0.312 to 2.5 mg/mL, highlighting the lowest values attained for the derivatives containing methoxy, chlorine and benzofurane functional groups. The viability of aerobic bacteria was determined with the Tetrazolium/Formazan Test, a method that was found to be the best alternative approach with respect to the difuzimetric method. Seeds of Triticum aestivum L. were used for the evaluation of the germination indicators, such as seed germination (SG), the relative seed germination (RSG), the relative radicle growth (RRG), and the seed germination index (GI). The toxicity studies of QAs 1, 4 and 7, at two different concentrations, showed no inhibitory effect on seed germination.

Interaction of water-insoluble quaternary ammonium salts with the hydrated silica surface

1996 ◽  
Vol 32 (6) ◽  
pp. 331-334
Author(s):  
V. V. Turov ◽  
O. A. Zaporozhets ◽  
O. Yu. Nadzhafova ◽  
V. V. Sukhan
Keyword(s):  
Quaternary Ammonium ◽  
Silica Surface ◽  
Quaternary Ammonium Salts ◽  
Ammonium Salts ◽  
Hydrated Silica
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