Effects of evaporation in the ignition of damp wood in a flowing gaseous oxidant

G. N. Isakov; G. S. Kas'yanov

doi:10.1007/bf00749257

Abrupt but smaller than expected changes in surface air quality attributable to COVID-19 lockdowns

Science Advances ◽

10.1126/sciadv.abd6696 ◽

2021 ◽

Vol 7 (3) ◽

pp. eabd6696

Author(s):

Zongbo Shi ◽

Congbo Song ◽

Bowen Liu ◽

Gongda Lu ◽

Jingsha Xu ◽

...

Keyword(s):

Air Quality ◽

Air Pollutant ◽

Pollutant Emissions ◽

Quality Improvements ◽

Learning Technique ◽

Emission Changes ◽

Almost All ◽

Gaseous Oxidant ◽

Sophisticated Analysis ◽

Limited Change

The COVID-19 lockdowns led to major reductions in air pollutant emissions. Here, we quantitatively evaluate changes in ambient NO2, O3, and PM2.5 concentrations arising from these emission changes in 11 cities globally by applying a deweathering machine learning technique. Sudden decreases in deweathered NO2 concentrations and increases in O3 were observed in almost all cities. However, the decline in NO2 concentrations attributable to the lockdowns was not as large as expected, at reductions of 10 to 50%. Accordingly, O3 increased by 2 to 30% (except for London), the total gaseous oxidant (Ox = NO2 + O3) showed limited change, and PM2.5 concentrations decreased in most cities studied but increased in London and Paris. Our results demonstrate the need for a sophisticated analysis to quantify air quality impacts of interventions and indicate that true air quality improvements were notably more limited than some earlier reports or observational data suggested.

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An Asymptotic, Thermo-Diffusive Ignition Theory of Porous Solid Fuels

Journal of Heat Transfer ◽

10.1115/1.3450530 ◽

1976 ◽

Vol 98 (2) ◽

pp. 269-275 ◽

Cited By ~ 4

Author(s):

Choong Se Kim ◽

Paul M. Chung

Keyword(s):

Nonlinear Partial Differential Equations ◽

Porous Solid ◽

Solid Fuels ◽

Thermal Ignition ◽

Mass Balances ◽

Governing Equations ◽

Order Ordinary Differential Equation ◽

First Order ◽

Time Space ◽

Gaseous Oxidant

The governing equations of thermal ignition are analyzed for porous solid fuel, such as coal, of various two-dimensional and axisymmetric geometries by the Laplace asymptotic method. Mass diffusion of the gaseous oxidant through the porous fuel is included. The nonlinear partial differential equations of energy and mass balances in time-space coordinates containing the Arrhenius volumic chemical reaction terms are analyzed. By employing the Laplace asymptotic technique and by invoking a certain limit theorem, the governing equations are reduced to a first order ordinary differential equation governing the fuel surface temperature, which is readily solved numerically. Detailed discussion of the effects of the various governing parameters on ignition is presented. Because of the basically closed-form nature of the solutions obtained, many general and fundamental aspects of the ignition criteria hitherto unknown are found.

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The Effect of Potassium Carbonate on the Catalytic Properties for Methane Conversion with Ceria

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.161.194 ◽

2012 ◽

Vol 161 ◽

pp. 194-199

Author(s):

Yue Juan Duan ◽

Hua Wang ◽

Yong Gang Wei ◽

Kong Zhai Li ◽

Xing Zhu ◽

...

Keyword(s):

Solid Solution ◽

Storage Capacity ◽

Catalytic Properties ◽

Fixed Bed ◽

Oxygen Storage Capacity ◽

Fixed Bed Reactor ◽

Oxygen Storage ◽

Incipient Wetness Impregnation ◽

Solid Reaction ◽

Gaseous Oxidant

Pure CeO2and a series of (x %) K-CeO2(x=1, 2, 3, 4) catalysts were respectively prepared by the precipitation and incipient wetness impregnation methods, and characterized by means of XRD, BET and H2-TPR techniques. The catalytic activity was investigated by the gas-solid reaction with methane in the absence of gaseous oxidant in a fixed bed reactor at 800 °C. The XRD measurement showed that doping of K2CO3did not change the structure of CeO2with the addition of K2CO3 without formation of Ce-K-O solid solution in these materials. Surface area of catalysts wasSubscript textdecreased with the impregnation amount of K2CO3. Reducibility of catalysts was obviously enhanced by the addition of K2CO3as shown in H2-TPR tests. The catalysts activity tests indicated that adding K2CO3to CeO2could promote the oxygen storage capacity of catalysts. K species in CeO2could affect the CO formation in methane oxidation.

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Syngas Generation from Methane Using a Chemical-Looping Concept: A Review of Oxygen Carriers

Journal of Chemistry ◽

10.1155/2013/294817 ◽

2013 ◽

Vol 2013 ◽

pp. 1-8 ◽

Cited By ~ 6

Author(s):

Kongzhai Li ◽

Hua Wang ◽

Yonggang Wei

Keyword(s):

Oxygen Carrier ◽

Cost Savings ◽

Oxygen Storage ◽

Pure Oxygen ◽

Chemical Looping ◽

Oxygen Carriers ◽

Gaseous Oxygen ◽

Solid Oxides ◽

Oxidation Of Methane ◽

Gaseous Oxidant

Conversion of methane to syngas using a chemical-looping concept is a novel method for syngas generation. This process is based on the transfer of gaseous oxygen source to fuel (e.g., methane) by means of a cycling process using solid oxides as oxygen carriers to avoid direct contact between fuel and gaseous oxygen. Syngas is produced through the gas-solid reaction between methane and solid oxides (oxygen carriers), and then the reduced oxygen carriers can be regenerated by a gaseous oxidant, such as air or water. The oxygen carrier is recycled between the two steps, and the syngas with a ratio of H2/CO = 2.0 can be obtained successively. Air is used instead of pure oxygen allowing considerable cost savings, and the separation of fuel from the gaseous oxidant avoids the risk of explosion and the dilution of product gas with nitrogen. The design and elaboration of suitable oxygen carriers is a key issue to optimize this method. As one of the most interesting oxygen storage materials, ceria-based and perovskite oxides were paid much attention for this process. This paper briefly introduced the recent research progresses on the oxygen carriers used in the chemical-looping selective oxidation of methane (CLSOM) to syngas.

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