Dielectric properties of quenched and X-ray irradiated triglycine sulphate single crystals later excited with laser light

1992 ◽  
Vol 11 (19) ◽  
pp. 1312-1314 ◽  
Author(s):  
P. Selvarajan ◽  
B. N. Das ◽  
H. B. Gon ◽  
K. V. Rao
Author(s):  
Elena V. Selezneva ◽  
Irina P. Makarova ◽  
Inna A. Malyshkina ◽  
Nadezhda D. Gavrilova ◽  
Vadim V. Grebenev ◽  
...  

Investigations of new single crystals grown in the K3H(SO4)2–(NH4)3H(SO4)2–H2O system from solutions with different K:NH4 concentration ratios have been carried out. Based on the X-ray diffraction data, the atomic structure of the crystals was determined at room temperature taking H atoms into account. It has been determined that [K0.43(NH4)0.57]3H(SO4)2 crystals are trigonal at ambient conditions such as the superprotonic phase of (NH4)3H(SO4)2 at high temperature. A distribution of the K and N atoms in the crystal was modelled on the basis of the refined occupancies of K/N positions. Studies of dielectric properties over the temperature range 223–353 K revealed high values of conductivity of the crystals comparable with the conductivity of known superprotonic compounds at high temperatures, and an anomaly corresponding to a transition to the phase with low conductivity upon cooling.


Author(s):  
J. Schreuer ◽  
T. Münch

AbstractLarge single crystals of optical quality of monoclinic ethylenediammonium bis(hydrogensuccinate) were grown from aqueous solutions. An X-ray structure analysis yielded space group


1981 ◽  
Vol 64 (1) ◽  
pp. 413-417 ◽  
Author(s):  
D. P. Yadav ◽  
H. N. Acharya ◽  
K. V. Rao

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