The structure and thermodynamic properties of water II. The structure of water at the triple point

1967 ◽  
Vol 7 (1) ◽  
pp. 6-11
Author(s):  
Yu. V. Gurikov
1974 ◽  
Vol 52 (16) ◽  
pp. 1521-1531 ◽  
Author(s):  
J. Ancsin

Boiling points, freezing points, and vapor pressures (from 56 K to the normal boiling point) for pure and various doped N2 samples have been measured. The normal boiling points for N2 and N2 doped with 100 v.p.p.m. of O2, Ar, Kr, and CO impurities were found to be 77.3439 K, 77.3458 K, 77.3452 K, 77.3454 K, and 77.3444 K respectively. The triple points of the same samples are 63.14635 K, 63.1445 K, 63.14575 K, 63.1487 K, and 63.14675 K respectively. The values obtained for the heats of sublimation, vaporization, and fusion at the triple point of pure N2 were 6773.8, 6049.6, and 724.3 J/mole respectively and the above impurities changed these quantities by the amounts given in Tables 5 and 6.


2016 ◽  
Vol 52 (1) ◽  
Author(s):  
L. N. Yakub ◽  
O. S. Bodiul

The theoretical equation of state for solid methane, developed within the framework of perturbation theory, with the crystal consisting of spherical molecules as zero-order approximation, and octupole – octupole interaction of methane molecules as a perturbation, is proposed. Thermodynamic functions are computed on the sublimation line up to the triple point. The contribution of the octupole – octupole interaction to the thermodynamic properties of solid methane is estimated.


1969 ◽  
Vol 47 (23) ◽  
pp. 2709-2713 ◽  
Author(s):  
R. O. Watts

The radial distribution function and thermodynamic properties of argon are calculated using the (12, 6) potential and the Percus–Yevick approximation. The results are compared with experimental values for argon, the machine calculations of Verlet and of McDonald and Singer, and with the perturbation theory of Barker and Henderson.


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