Effectiveness of Ionol as an antioxidant additive for jet fuels at elevated temperatures

1977 ◽  
Vol 13 (6) ◽  
pp. 384-386
Author(s):  
A. A. Gureev ◽  
N. Ya. Chertkova
1979 ◽  
Vol 15 (3) ◽  
pp. 166-168
Author(s):  
Ya. B. Chertkov ◽  
E. P. Seregin ◽  
R. M. Berezina ◽  
E. A. Kunina ◽  
T. I. Kirsanova

Author(s):  
Александр Николаевич Болотов ◽  
Ольга Олеговна Новикова ◽  
Владислав Викторович Новиков

Известные в настоящее время магнитные смазочные наножидкости имеют недостаточно хорошие триботехнические характеристики при эксплуатации в режиме граничного трения. Предложен способ адаптации для граничного трения магнитных силоксановых наножидкостей, путем модификации их состава химически активными антифрикционными, противоизносными и противозадирными присадками. Создан ряд смазочных композиций магнитных наножидкости на основе полиэтилсилоксана ПЭС-5. Поведенные экспериментальные исследования показали, что наиболее значительное улучшение антифрикционных и противоизносных свойств наножидкостей достигается при введении в их структуру хлорсодержащих присадок Совол и 3Н2ТЭ. Добавление в наножидкость антиокислительной присадки ДФ-11, фторсодержащей присадки ЭО-1, металлоплакирующего соединения МКФ-18 не привело к значимому улучшению антифрикционных свойств. Установлено, что магнитные наножидкости с модифицирующими присадками, по трибосвойствам сопоставимы с традиционными немагнитными жидкими смазочными материалами и превосходят пластичные смазки на основе полиэтилсилоксана. Разработанные композиции на основе силоксановых наножидкостей, будут востребованы для смазывания подшипников качения и скольжения, зубчатых передач, контактных уплотнений, которые функционируют при низких и повышенных температурах в газовой среде или в условиях вакуума. Наиболее успешно они могут применяться в вакуумной и космической технике, для магнитных трибоузлов, где возможна только однократная заправка ограниченным объемом смазочного материала. Currently known magnetic lubricant nanofluids have insufficiently good tribological characteristics when operating in the boundary friction mode. An adaptation method is proposed for the boundary friction of magnetic siloxane nanofluids by modifying their composition with chemically active antifriction, antiwear and extreme pressure additives. A number of lubricating compositions of magnetic nanofluids based on polyethylsiloxane PES-5 have been created. Conducted experimental studies have shown that the most significant improvement in the antifriction and antiwear properties of nanofluids is achieved with the introduction of Sovol and 3N2TE chlorine additives into their structure. Adding to the nanofluid the antioxidant additive DF-11, the fluorine-containing additive EO-1, the metal-plating compound MKF-18 did not lead to a significant improvement in the antifriction properties. It has been established that magnetic nanofluids with modifying additives are comparable in tribological properties with traditional non-magnetic liquid lubricants and are superior to plastic lubricants based on polyethylsiloxane. The developed compositions based on siloxane nanofluids will be in demand for lubrication of rolling and sliding bearings, gears, contact seals, which operate at low and elevated temperatures in a gas environment or in a vacuum. Most successfully, they can be used in vacuum and space technology, for magnetic frictional units, where only one refueling with a limited amount of lubricant is possible.


Author(s):  
N. M. P. Low ◽  
L. E. Brosselard

There has been considerable interest over the past several years in materials capable of converting infrared radiation to visible light by means of sequential excitation in two or more steps. Several rare-earth trifluorides (LaF3, YF3, GdF3, and LuF3) containing a small amount of other trivalent rare-earth ions (Yb3+ and Er3+, or Ho3+, or Tm3+) have been found to exhibit such phenomenon. The methods of preparation of these rare-earth fluorides in the crystalline solid form generally involve a co-precipitation process and a subsequent solid state reaction at elevated temperatures. This investigation was undertaken to examine the morphological features of both the precipitated and the thermally treated fluoride powders by both transmission and scanning electron microscopy.Rare-earth oxides of stoichiometric composition were dissolved in nitric acid and the mixed rare-earth fluoride was then coprecipitated out as fine granules by the addition of excess hydrofluoric acid. The precipitated rare-earth fluorides were washed with water, separated from the aqueous solution, and oven-dried.


Author(s):  
J. L. Brimhall ◽  
H. E. Kissinger ◽  
B. Mastel

Some information on the size and density of voids that develop in several high purity metals and alloys during irradiation with neutrons at elevated temperatures has been reported as a function of irradiation parameters. An area of particular interest is the nucleation and early growth stage of voids. It is the purpose of this paper to describe the microstructure in high purity nickel after irradiation to a very low but constant neutron exposure at three different temperatures.Annealed specimens of 99-997% pure nickel in the form of foils 75μ thick were irradiated in a capsule to a total fluence of 2.2 × 1019 n/cm2 (E > 1.0 MeV). The capsule consisted of three temperature zones maintained by heaters and monitored by thermocouples at 350, 400, and 450°C, respectively. The temperature was automatically dropped to 60°C while the reactor was down.


Author(s):  
Robert C. Rau ◽  
Robert L. Ladd

Recent studies have shown the presence of voids in several face-centered cubic metals after neutron irradiation at elevated temperatures. These voids were found when the irradiation temperature was above 0.3 Tm where Tm is the absolute melting point, and were ascribed to the agglomeration of lattice vacancies resulting from fast neutron generated displacement cascades. The present paper reports the existence of similar voids in the body-centered cubic metals tungsten and molybdenum.


Author(s):  
Ernest L. Hall ◽  
J. B. Vander Sande

The present paper describes research on the mechanical properties and related dislocation structure of CdTe, a II-VI semiconductor compound with a wide range of uses in electrical and optical devices. At room temperature CdTe exhibits little plasticity and at the same time relatively low strength and hardness. The mechanical behavior of CdTe was examined at elevated temperatures with the goal of understanding plastic flow in this material and eventually improving the room temperature properties. Several samples of single crystal CdTe of identical size and crystallographic orientation were deformed in compression at 300°C to various levels of total strain. A resolved shear stress vs. compressive glide strain curve (Figure la) was derived from the results of the tests and the knowledge of the sample orientation.


Author(s):  
Afzana Anwer ◽  
S. Eilidh Bedford ◽  
Richard J. Spontak ◽  
Alan H. Windle

Random copolyesters composed of wholly aromatic monomers such as p-oxybenzoate (B) and 2,6-oxynaphthoate (N) are known to exhibit liquid crystalline characteristics at elevated temperatures and over a broad composition range. Previous studies employing techniques such as X-ray diffractometry (XRD) and differential scanning calorimetry (DSC) have conclusively proven that these thermotropic copolymers can possess a significant crystalline fraction, depending on molecular characteristics and processing history, despite the fact that the copolymer chains possess random intramolecular sequencing. Consequently, the nature of the crystalline structure that develops when these materials are processed in their mesophases and subsequently annealed has recently received considerable attention. A model that has been consistent with all experimental observations involves the Non-Periodic Layer (NPL) crystallite, which occurs when identical monomer sequences enter into register between adjacent chains. The objective of this work is to employ electron microscopy to identify and characterize these crystallites.


Author(s):  
C. W. Allen ◽  
D. L. Kuruzar

The rare earth/transition element intermetallics R2T17 are essentially topologically close packed phases for which layer structure models have already been presented. Many of these compounds are known to undergo allotropic transformation of the type at elevated temperatures. It is not unexpected that shear transformation mechanisms are involved in view of the layering character of the structures. The transformations are evidently quite sluggish, illustrated in furnace cooled Dy2Co17 by the fact that only rarely has the low temperature rhombohedral form been seen. The more usual structures observed so far in furnace cooled alloys include 4H and 6H in Dy2Co17 (Figs. 1 and 2) . In any event it is quite clear that the general microstructure is very complicated as a consequence of the allotropy, illustrated in Fig. 3. Numerous planar defects in the layer plane orientation are evident as are non-layer plane defects inherited from a high temperature structure.


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