Ionization constants for very weak organic acids in aqueous solution and apparent ionization constants for water in aqueous organic mixtures

1972 ◽  
Vol 1 (4) ◽  
pp. 341-351 ◽  
Author(s):  
Earl M. Woolley ◽  
Jay Tomkins ◽  
Loren G. Hepler
1987 ◽  
Vol 155 (1) ◽  
pp. 115-124 ◽  
Author(s):  
R.K. Nigam ◽  
K.C. Singh ◽  
Sanjeev Maken

1994 ◽  
Vol 50 (2) ◽  
pp. 185-190 ◽  
Author(s):  
V. Venugopal ◽  
S.N. Doke ◽  
P.M. Nair

1990 ◽  
Vol 26 (2) ◽  
pp. 159-167 ◽  
Author(s):  
J. M. Solis ◽  
A. S. Herranz ◽  
O. Herreras ◽  
N. Menéndez ◽  
R. Martin del Rio

1960 ◽  
Vol 38 (3) ◽  
pp. 399-406 ◽  
Author(s):  
Ross Stewart ◽  
R. Van der Linden

A series of five trifluoroacetophenones and five phenyl trifluoromethyl carbinols have been synthesized and their ionization constants in water measured. They are the unsubstituted, p-methoxy, p-methyl, m-bromo, and m-nitro compounds. The ketones exist as hydrates in aqueous solution and each is about two pK units stronger than the corresponding alcohol. The acidities of both series are correlated by the Hammett relation with ρ values of 1.11 and 1.01 for the ketone hydrates and alcohols respectively. The acid strengths vary from a pKa of 9.18 for m-nitro-α,α,α-trifluoroacetophenone to 12.24 for p-methoxyphenyl trifluoromethyl carbinol.


Desalination ◽  
2002 ◽  
Vol 149 (1-3) ◽  
pp. 399-404 ◽  
Author(s):  
H. Roux-de Balmann ◽  
M. Bailly ◽  
F. Lutin ◽  
P. Aimar

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