Thermal stability of a solid solution of hydrogen in certain transition metals

1975 ◽  
Vol 9 (4) ◽  
pp. 461-462
Author(s):  
I. S. Slabkovskii
Keyword(s):  
Thermal Stability ◽  
Solid Solution ◽  
Transition Metals ◽  
Thermal Stability Of

Achieving high thermal stability of different rare-earth ions in a single matrix host via the manipulation of the local structure by a solid solution

2020 ◽  
Vol 22 (28) ◽  
pp. 16294-16300
Author(s):  
Xiuxia Yang ◽  
Lei Zhao ◽  
Zhichao Liu ◽  
Shuyu Tian ◽  
Hao Zhang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Solid Solution ◽  
Rare Earth ◽  
Local Structure ◽  
Local Environment ◽  
High Thermal Stability ◽  
Rare Earth Ions ◽  
Single Matrix ◽  
Thermal Stability Of

Manipulating the local environment of CAS by substitution of Al3+–Y3+ for Si4+–Ca2+ to achieve more stability in the structure of CYA.

Thermal Decomposition of Supersaturated Ti1-xAlxN Solid Solution Synthesized by High-Energy Milling

2016 ◽  
Vol 9 ◽  
pp. 82-89
Author(s):  
Maya Radune ◽  
Michael Zinigrad ◽  
David Fuks ◽  
S. Hayun ◽  
Nachum Frage
Keyword(s):  
Thermal Stability ◽  
Solid Solution ◽  
Spinodal Decomposition ◽  
Density Functional ◽  
Chemical Deposition ◽  
High Energy ◽  
Nucleation And Growth ◽  
Scanning Calorimetry ◽  
Wide Range ◽  
Thermal Stability Of

Supersaturated titanium-aluminum nitride (Ti1-xAlxN) is a very attractive material for a wide range of applications due to its high oxidation and wear resistance accompanied by high strength, hardness, thermal conductivity and thermal shock resistance. Currently, its applications are limited to coatings obtained by physical or chemical deposition. Bulk materials based on Ti1-xAlxN may be fabricated by powder metallurgy approach using powders synthesized by high-energy ball milling (HEBM), which composition corresponds to supersaturated Ti1-xAlxN solid solution. In the present study, thermal stability of the supersaturated Ti1-xAlxN solid solution was investigated. According to the quasi-binary TiN-AlN phase diagram, constructed using density functional theory (DFT) analysis, the concentration ranges, where decomposition takes place through spinodal decomposition or through nucleation and growth, were determined. Experimental study on thermal stability of solid Ti1-xAlxN solution powder was conducted by means of differential scanning calorimetry (DSC), Brunauer-Emmited-Teller (BET) and XRD. The results indicated that spinodal decomposition of Ti1-xAlxN starts at 800°C, while at temperature higher than 1300°C regular decomposition (nucleation and growth) is occur.

Effect of solid solution of thermal stability of zircon

1970 ◽  
Vol 5 (11) ◽  
pp. 965-972 ◽  
Author(s):  
S.S. Ramakrishnan ◽  
E.C. Subbarao ◽  
K.V.G.K. Gokhale
Keyword(s):  
Thermal Stability ◽  
Solid Solution ◽  
Thermal Stability Of

Preventing sintering of nanoclusters on graphene by radical adsorption

Nanoscale ◽  
2017 ◽  
Vol 9 (36) ◽  
pp. 13618-13629 ◽  
Author(s):  
A. J. Martínez-Galera ◽  
U. A. Schröder ◽  
C. Herbig ◽  
M. A. Arman ◽  
J. Knudsen ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Transition Metals ◽  
Radical Adsorption ◽  
Thermal Stability Of

The thermal stability of monodisperse transition metals nanoparticles on graphene is improved by exposure to radicals.

Thermal Stability of Rapidly Solidified Alloys of Aluminium with Transition Metals

2006 ◽  
Vol 519-521 ◽  
pp. 389-394 ◽  
Author(s):  
Dalibor Vojtěch ◽  
Jan Verner ◽  
Barbora Bártová ◽  
Karel Saksl
Keyword(s):  
Thermal Stability ◽  
Transition Metals ◽  
Solid Solutions ◽  
Melt Spinning ◽  
Structural Features ◽  
High Thermal Stability ◽  
Crystalline Phases ◽  
Supersaturated Solid Solutions ◽  
Rapidly Solidified ◽  
Thermal Stability Of

Rapidly solidified (RS) Al-TM (TM = transition metal) alloys are perspective materials from scientific, as well as technological point of view. Generally, they are produced by the melt atomization or by the melt spinning. Subsequent compaction is commonly performed by the hot extrusion. Since transition metals, such as Cr, Fe, Ni, Zr, Ti, Mn and others, have low diffusion coefficients in solid aluminium (lower by several orders of magnitude than those of common alloying elements like Cu, Si, Mg, Zn etc.) the RS Al-TM alloys are characterized by a high thermal stability. In this paper, several RS Al-TM (TM = Cr, Fe, Ti, Mn, Ni) alloys prepared by the melt spinning and melt atomization are compared to commercially available 2xxx, 6xxx and 7xxx wrought alloys. The main structural features of both RS and wrought alloys are described. The RS alloys are characterized by the presence of micro and nano-scale crystalline and/or quasi-crystalline phases and supersaturated solid solutions. The elevated-temperature behaviour is compared for both groups of materials. The thermal stability of the investigated materials is determined by room temperature hardness measurements after various annealing regimes and a high thermal stability of the RS alloys is demonstrated. The microstructural changes and phase transformations occurring in the investigated materials upon heating are described. In the Al-TM alloys, very slow decomposition of the supersaturated solid solutions, precipitation and decomposition of the metastable quasi-crystalline phases occur.

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