Novel monoaza- and diazacrown ethers incorporating sugar units and their extraction ability towards picrate salts

1995 ◽  
Vol 23 (3) ◽  
pp. 195-201 ◽  
Author(s):  
P�ter Bak� ◽  
L�szl� T�ke
Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 919
Author(s):  
Wanlu Jiang ◽  
Chenyang Wang ◽  
Jiayun Zou ◽  
Shuqing Zhang

The field of mechanical fault diagnosis has entered the era of “big data”. However, existing diagnostic algorithms, relying on artificial feature extraction and expert knowledge are of poor extraction ability and lack self-adaptability in the mass data. In the fault diagnosis of rotating machinery, due to the accidental occurrence of equipment faults, the proportion of fault samples is small, the samples are imbalanced, and available data are scarce, which leads to the low accuracy rate of the intelligent diagnosis model trained to identify the equipment state. To solve the above problems, an end-to-end diagnosis model is first proposed, which is an intelligent fault diagnosis method based on one-dimensional convolutional neural network (1D-CNN). That is to say, the original vibration signal is directly input into the model for identification. After that, through combining the convolutional neural network with the generative adversarial networks, a data expansion method based on the one-dimensional deep convolutional generative adversarial networks (1D-DCGAN) is constructed to generate small sample size fault samples and construct the balanced data set. Meanwhile, in order to solve the problem that the network is difficult to optimize, gradient penalty and Wasserstein distance are introduced. Through the test of bearing database and hydraulic pump, it shows that the one-dimensional convolution operation has strong feature extraction ability for vibration signals. The proposed method is very accurate for fault diagnosis of the two kinds of equipment, and high-quality expansion of the original data can be achieved.


2004 ◽  
Vol 847 ◽  
Author(s):  
Sébastien Anthérieu ◽  
Florence Brodard-Séverac ◽  
Gilles Guerrero ◽  
P. Hubert Mutin

ABSTRACTTitania particles (P25 DEGUSSA AG) were treated by a solution of 12-mercaptododecyl-phosphonic acid (MDPA) in toluene to obtain an organic-inorganic hybrid material with thiol functions at the surface. This material was characterized by chemical analysis, solid state 31P MAS NMR and FTIR spectroscopies, and XPS. Reaction of the phosphonic acid end of MDPA with the TiO2 surface led to the formation of a relatively dense and well-ordered self-assembled monolayer (SAM), with a density of about 3.9 SH functions per nm2. This material was tested for the extraction of mercury in water at pH 7, 9, and 11. Chemical analysis indicated no loss of SH functionality, even at pH 11. The best extraction results were obtained at pH 9 and 11, with a metal extraction ability between 85 and 90%.


Nanomaterials ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 720 ◽  
Author(s):  
Hang Dong ◽  
Shangzheng Pang ◽  
Yi Zhang ◽  
Dazheng Chen ◽  
Weidong Zhu ◽  
...  

Due to the low temperature fabrication process and reduced hysteresis effect, inverted p-i-n structured perovskite solar cells (PSCs) with the PEDOT:PSS as the hole transporting layer and PCBM as the electron transporting layer have attracted considerable attention. However, the energy barrier at the interface between the PCBM layer and the metal electrode, which is due to an energy level mismatch, limits the electron extraction ability. In this work, an inorganic aluminum-doped zinc oxide (AZO) interlayer is inserted between the PCBM layer and the metal electrode so that electrons can be collected efficiently by the electrode. It is shown that with the help of the PCBM/AZO bilayer, the power conversion efficiency of PSCs is significantly improved, with negligible hysteresis and improved device stability. The UPS measurement shows that the AZO interlayer can effectively decrease the energy offset between PCBM and the metal electrode. The steady state photoluminescence, time-resolved photoluminescence, transient photocurrent, and transient photovoltage measurements show that the PSCs with the AZO interlayer have a longer radiative carrier recombination lifetime and more efficient charge extraction efficiency. Moreover, the introduction of the AZO interlayer could protect the underlying perovskite, and thus, greatly improve device stability.


2017 ◽  
Vol 82 (11) ◽  
pp. 1287-1302 ◽  
Author(s):  
Jelena Vuksanovic ◽  
Nina Todorovic ◽  
Mirjana Kijevcanin ◽  
Slobodan Serbanovic ◽  
Ivona Radovic

The ability of non-toxic and biodegradable deep eutectic solvent (DES) choline chloride + DL-malic acid in mole ratio 1:1, for the breaking of the azeotropes heptane + methanol and toluene + methanol by means of liquid? ?liquid extraction was evaluated. Ternary liquid?liquid equilibrium experiments were performed at 298.15 K and at atmospheric pressure. Densities, viscosities and refractive indices of DES + methanol and water + DES systems were experimentally determined over a wide temperature range and at atmospheric pressure. Additionally, the viscosities of DES + glycerol mixture were - determined at temperatures up to 363.15 K to check how much the addition of glycerol decreases high viscosities of DES. The results indicate that the addition of small amounts of water or glycerol as a third component significantly decreases the viscosity of the investigated deep eutectic solvent. Based on the selectivity and distribution ratio values, the extraction ability of the investigated deep eutectic solvent, in comparison with the conventionally used solvents, yields promising results. Non-random two-liquid (NRTL) and universal quasichemical (UNIQUAC) models were satisfactorily applied for correlation of experimental phase equilibrium data for two ternary mixtures.


2018 ◽  
Vol 34 (8) ◽  
pp. 973-978 ◽  
Author(s):  
Maria ATANASSOVA ◽  
Hiroyuki OKAMURA ◽  
Ayano EGUCHI ◽  
Yuki UEDA ◽  
Tsuyoshi SUGITA ◽  
...  
Keyword(s):  

Sensors ◽  
2020 ◽  
Vol 20 (7) ◽  
pp. 1841
Author(s):  
Linjie Li ◽  
Mian Zhang ◽  
Kesheng Wang

Deep learning-based intelligent fault diagnosis methods have attracted increasing attention for their automatic feature extraction ability. However, existing works are usually under the assumption that the training and test dataset share similar distributions, which unfortunately always violates real practice due to the variety of working conditions. In this paper, an end-to-end scheme of joint use of two-direction signals and capsule network (CN) is proposed for fault diagnosis of rolling bearing. With the help of the superior ability of CN in capturing the spatial position information between features, more valuable information can be mined. Aiming to eliminate the influence of different rotational speeds, vertical and horizontal vibration signals are fused as the input to CN, so that invariant features can be extracted automatically from the raw signals. The effectiveness of the proposed method is verified by experimental data of rolling bearing under different rotational speeds and compared with a deep convolutional neural network (DCNN). The results demonstrate that the proposed scheme is able to recognize the fault types of rolling bearing under scenarios of different rotational speeds.


Entropy ◽  
2019 ◽  
Vol 21 (2) ◽  
pp. 170 ◽  
Author(s):  
Xianzhi Wang ◽  
Shubin Si ◽  
Yu Wei ◽  
Yongbo Li

Multi-scale permutation entropy (MPE) is a statistic indicator to detect nonlinear dynamic changes in time series, which has merits of high calculation efficiency, good robust ability, and independence from prior knowledge, etc. However, the performance of MPE is dependent on the parameter selection of embedding dimension and time delay. To complete the automatic parameter selection of MPE, a novel parameter optimization strategy of MPE is proposed, namely optimized multi-scale permutation entropy (OMPE). In the OMPE method, an improved Cao method is proposed to adaptively select the embedding dimension. Meanwhile, the time delay is determined based on mutual information. To verify the effectiveness of OMPE method, a simulated signal and two experimental signals are used for validation. Results demonstrate that the proposed OMPE method has a better feature extraction ability comparing with existing MPE methods.


Author(s):  
Shinichi ITOH ◽  
Chunbin LI ◽  
Manabu YAMADA ◽  
Mitsuhiro AKAMA ◽  
Yoshifumi SHIMAKAWA ◽  
...  

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