Kinetics of proton exchange between semiquinone radicals and hydrochloric acid

1993 ◽  
Vol 42 (1) ◽  
pp. 74-77 ◽  
Author(s):  
A. S. Masalimov ◽  
L. E. Melbardis ◽  
A. I. Prokof'ev
Keyword(s):  
Hydrochloric Acid ◽  
Proton Exchange ◽  
Semiquinone Radicals ◽  
Kinetics Of

Kinetics of cyclization of S-ethoxycarbonylmethylisothiouronium chloride to 2-imino-4-thiazolidone

1979 ◽  
Vol 44 (3) ◽  
pp. 912-917 ◽  
Author(s):  
Vladimír Macháček ◽  
Said A. El-bahai ◽  
Vojeslav Štěrba
Keyword(s):  
Hydrochloric Acid ◽  
Dilute Hydrochloric Acid ◽  
Base Catalysis ◽  
General Base ◽  
Rate Limiting Step ◽  
Limiting Step ◽  
Kinetics Of Formation ◽  
Acid Catalyzed ◽  
Rate Limiting ◽  
Kinetics Of

Kinetics of formation of 2-imino-4-thiazolidone from S-ethoxycarbonylmethylisothiouronium chloride has been studied in aqueous buffers and dilute hydrochloric acid. The reaction is subject to general base catalysis, the β value being 0.65. Its rate limiting step consists in acid-catalyzed splitting off of ethoxide ion from dipolar tetrahedral intermediate. At pH < 2 formation of this intermediate becomes rate-limiting; rate constant of its formation is 2 . 104 s-1.

scholarly journals Kinetics of Substituted Bis- and Mono-azo Dyes as Corrosion Inhibitors for Aluminium in Hydrochloric Acid and Sodium Hydroxide Solutions

1999 ◽  
Vol 23 (7) ◽  
pp. 408-409
Author(s):  
Loutfy H. Madkour ◽  
R. M. Issa ◽  
I. M. El-Ghrabawy
Keyword(s):  
Hydrochloric Acid ◽  
Sodium Hydroxide ◽  
Azo Dyes ◽  
Thermodynamic Model ◽  
Corrosion Inhibitors ◽  
Kinetics Of ◽  
Alkaline Corrosion

This investigation is designed to apply an advanced kinetic–thermodynamic model on the data obtained from acidic and alkaline corrosion of aluminium using bis- and mono-azo dyes as corrosion inhibitors.

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