On the theory of adsorption kinetics of ionic sufactants at fluid interfaces 4. Deceleration of the adsorption rate due to non-equilibrium distribution of adsorbed ions in the diffuse layer

1994 ◽  
Vol 272 (5) ◽  
pp. 548-553 ◽  
Author(s):  
R. Miller ◽  
G. Kretzschmar ◽  
S. S. Dukhin
Keyword(s):  
Adsorption Kinetics ◽  
Equilibrium Distribution ◽  
Adsorption Rate ◽  
Diffuse Layer ◽  
Fluid Interfaces ◽  
Kinetics Of ◽  
Non Equilibrium

Study on the Formaldehyde Adsorption Kinetics of Dry Waters

2014 ◽  
Vol 809-810 ◽  
pp. 907-911
Author(s):  
Jun Long Wang ◽  
Jie Hou ◽  
Ting Jiang ◽  
Yong Jun He ◽  
Yao Dong Liang
Keyword(s):  
Adsorption Kinetics ◽  
High Speed ◽  
Adsorption Process ◽  
Average Diameter ◽  
Adsorption Rate ◽  
Absorption Kinetics ◽  
Order Model ◽  
Pseudo Second Order ◽  
Kinetics Of ◽  
Formaldehyde Adsorption

Dry waters with an average diameter of 82 μm were prepared by a high speed mixed route. The formaldehyde absorption kinetics of dry waters was investigated by simulating indoor formaldehyde pollution in glass chamber. The results showed that pseudo-second order model could be used to simulate the adsorption process; the adsorption rate was highest in the initial 60 minutes; when the adsorption lasted for 180 minutes, the adsorption reached equilibrium.

On the theory of adsorption kinetics of ionic surfactants at fluid interfaces

1985 ◽  
Vol 263 (5) ◽  
pp. 420-423 ◽  
Author(s):  
R. Miller ◽  
S. S. Dukhin ◽  
G. Kretzschmar
Keyword(s):  
Adsorption Kinetics ◽  
Ionic Surfactants ◽  
Fluid Interfaces ◽  
Kinetics Of

scholarly journals KINETIC STUDY ON ADSORPTION OF CHROMIUM(lIl) TO DIATOMACEOUS EARTH PRE-TREATED WITH SULFURIC AND HYDROCHLORIC ACIDS

2010 ◽  
Vol 3 (1) ◽  
pp. 32-38
Author(s):  
Nuryono Nuryono ◽  
V.V.H. Susanti ◽  
Narsito Narsito
Keyword(s):  
Rate Constant ◽  
Adsorption Kinetics ◽  
Diatomaceous Earth ◽  
Atomic Absorption Spectrophotometry ◽  
Adsorption Rate ◽  
Physical Interaction ◽  
Kinetics Of Adsorption ◽  
Pre Treatment ◽  
Sulfuric And Hydrochloric Acids ◽  
Kinetics Of

In this research, the effect of Sangiran diatomaceous earth pre-treatment with sulfuric acid (H2SO4) and hydrochloric acid (HCl) on the kinetics of adsorption for Cr(III) in aqueous solution has been studied. The research has been carried out by mixing an amount of diatomeaeous earth with HCl or H2SO4 in various concentrations for two hours at temperature of 150 - 200°C. The mixture was washed with water until neutral, and the residue was dried at 70°C for four hours. The result then was used as adsorbent. Adsorption was carried out by mixing an amount of adsorbent with Cr(III) solution in various contact times. Ion adsorbed was determined by analyzing filtrate using atomic absorption spectrophotometry. The effect of pre-treatment on adsorption kinetics was evaluated based on kinetic parameters, i.e. constant of adsorption rate by using Langmuir-Hinshelwood kinetics and using two-process kinetics (fast and slow processes). Adsorption kinetics calculated using LH equation gave negative value for adsorption rate constant of zero order (k0). On the other words, the LH kinetics might not be applied for adsorption of Cr(III) to diatomaceous earth adsorbent. Results of kinetics study approached using two processes (fast and slow) showed that adsorption of Cr(III) occurred in two processes with rate constant of fast adsorption, kc, 0.041/min, rate constant of slow adsorption, kl, 0.0089/min, and of slow desorption, k'l, 0.089/menit. Pre-treatment with HCl up to 10 M decreased either kc, kl or k'l, while pre-treatment with H2SO4 1M increased kc to 0.061/min, decreased kl to 0.00424 and k'l to 0.0139/min. On pre-treatment with H2SO4 higher than 6 M significantly decreased three constants above. Based on the Gibbs energy change (4.31 - 6.79 kJ/mole) showed that adsorption involved physical interaction.   Keywords: adsorption, chromium, diatomaceous earth, kinetics, Langmuir-Hinshelwood

Role of electrostatic interactions in the adsorption kinetics of nanoparticles at fluid–fluid interfaces

2016 ◽  
Vol 18 (7) ◽  
pp. 5499-5508 ◽  
Author(s):  
Venkateshwar Rao Dugyala ◽  
Jyothi Sri Muthukuru ◽  
Ethayaraja Mani ◽  
Madivala G. Basavaraj
Keyword(s):  
Surface Tension ◽  
Adsorption Kinetics ◽  
Electrostatic Interaction ◽  
Electrostatic Interactions ◽  
Dynamic Surface Tension ◽  
Nano Particles ◽  
Fluid Interfaces ◽  
Dynamic Surface ◽  
Kinetics Of

The dynamic surface tension measurements are used to elucidate the contribution of electrostatic interaction energy barriers for the adsorption of nano-particles to the interfaces.

On the theory of adsorption kinetics of ionic surfactants at fluid interfaces

1983 ◽  
Vol 261 (4) ◽  
pp. 335-339 ◽  
Author(s):  
S. S. Dukhin ◽  
R. Miller ◽  
G. Kretzschmar
Keyword(s):  
Adsorption Kinetics ◽  
Ionic Surfactants ◽  
Fluid Interfaces ◽  
Kinetics Of

Adsorption Kinetics of Nickel Etioporphyrin on VTB-Asphaltene in N-Pentane Solution

2013 ◽  
Vol 781-784 ◽  
pp. 24-29
Author(s):  
Fei Fei Chen ◽  
Zhi Ming Xu ◽  
Xue Wen Sun ◽  
Suo Qi Zhao
Keyword(s):  
Adsorption Kinetics ◽  
Oil Sands ◽  
Removal Rate ◽  
Adsorption Rate ◽  
Low Molecular Weight ◽  
Pseudo Second Order ◽  
Alkane Solvents ◽  
Solvent Deasphalting ◽  
Oil Sands Bitumen ◽  
Kinetics Of

It is important to find out how to strengthen the interaction between nickel porphyrins and asphaltene in the alkane solvents of the low molecular weight for raising the removal rate of nickel in the solvent deasphalting process. Therefore, the adsorption kinetics, which describes how the nickel etioporphyrins are adsorbed on asphaltene (the vacuum residue of Canadian oil sands bitumen (VTB)) in the n-pentane solvent, are investigated. The results show that a certain amount of nickel porphyrins is absorbed on the asphaltene of VTB, which means there is a certain adsorption between asphaltene and nickel porphyrins. The adsorption rate is affected by the dosage of asphaltene, the concentration of the n-pentane solution containing nickel porphyrins and the temperature. A comparison in the four kinds of kinetic models on the overall adsorption rate shows that adsorption process can be perfectly described by the pseudo second-order equation.

scholarly journals ADSORPTION KINETICS OF Pb(II), Cd(II) AND Cr(III) ON ADSORBENT PRODUCED BY PROTECTED-CROSSLINKING OF HUMIC ACID-CHITOSAN

2010 ◽  
Vol 10 (1) ◽  
pp. 80-87
Author(s):  
Dewi Umaningrum ◽  
Uripto Trisno Santoso ◽  
Radna Nurmasari ◽  
Rahmat Yunus
Keyword(s):  
Humic Acid ◽  
Adsorption Kinetics ◽  
Metal Ion ◽  
Second Order ◽  
Adsorption Rate ◽  
Ion Concentration ◽  
Rate Limiting Step ◽  
Limiting Step ◽  
Rate Limiting ◽  
Kinetics Of

Study on adsorption kinetics of of Pb(II), Cd(II) and Cr(III) on adsorbent which was produced by protected-crosslinking of humic acid-chitosan has been done. The Langmuir-Hinshelwood, pseudo first- and second-order kinetics models were used to describe the kinetic data, and the rate constants of adsorption were also evaluated. The experimental data fitted well the second-order kinetics model, indicating that the chemical sorption is the rate-limiting step, instead of mass transfer. The initial metal ion concentration significantly affects the adsorption rate. An increase in initial metal ion concentration results in the decrease in adsorption rate of the metals.   Keywords: kinetics, adsorption, crosslinking, humic acid, chitosan

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