Ternary mutual diffusion coefficients of KCl-LaCl3-water mixtures from taylor dispersion profiles

1992 ◽  
Vol 21 (1) ◽  
pp. 15-22 ◽  
Author(s):  
Zhiping Deng ◽  
Derek G. Leaist
Keyword(s):  
Diffusion Coefficients ◽  
Taylor Dispersion ◽  
Mutual Diffusion

Diffusion Coefficients of Aqueous Solutions of Carbohydrates as Seen by Taylor Dispersion Technique at Physiological Temperature (37 °C)

2006 ◽  
Vol 258-260 ◽  
pp. 305-309 ◽  
Author(s):  
Ana C.F. Ribeiro ◽  
Cecilia Isabel A.V Santos ◽  
Victor M.M. Lobo ◽  
Artur J.M. Valente ◽  
Pedro M.R.A. Prazeres ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Concentration Dependence ◽  
Diffusion Coefficients ◽  
Taylor Dispersion ◽  
Mutual Diffusion ◽  
Physiological Temperature ◽  
Taylor Dispersion Technique ◽  
Dispersion Technique

Binary mutual diffusion coefficients have been measured for aqueous solutions of some carbohydrates (glucose, fructose, lactose, sucrose, α-cyclodextrin and β- cyclodextrin) at concentrations from 0.002 mol dm-3 to 0.010 mol dm-3. The concentration dependence of the diffusion coefficients at physiological temperature, 37 °C, is discussed on the basis of their structures.

Ternary mutual diffusion coefficients of MgCl2 + MgSO4 + H2O and Na2SO4 + MgSO4 + H2O from Taylor dispersion profiles

1991 ◽  
Vol 69 (10) ◽  
pp. 1548-1553 ◽  
Author(s):  
Zhipeng Deng ◽  
Derek G. Leaist
Keyword(s):  
Diffusion Coefficients ◽  
Multicomponent Diffusion ◽  
Taylor Dispersion ◽  
Mutual Diffusion ◽  
Salt Solutions ◽  
Mixed Salt ◽  
Ternary Diffusion ◽  
Peak Broadening ◽  
Ternary Diffusion Coefficients ◽  
Mixed Salt Solutions

The Taylor dispersion (peak-broadening) technique is used to measure the ternary mutual diffusion coefficients of the mixed salt solutions MgCl2 + MgSO4 + H2O and Na2SO4 + MgSO4 + H2O at 25 °C. The dispersion of the solutes is followed by differential refractometry. A simple least-squares procedure is developed to calculate the ternary diffusion coefficients from the refractive index profiles. The coefficients are measured at 0.04, 0.20, or 0.40 mol dm−3 total salt for the molar salt ratios 1:3, 1:1, or 3:1. The measured diffusion coefficients are compared with the limiting values for the completely dissociated salts. Key words: mixed salt solutions, multicomponent diffusion, Taylor dispersion, ternary diffusion coefficients.

Mutual Diffusion Coefficients of Aqueous KCl at High Pressures Measured by the Taylor Dispersion Method

2011 ◽  
Vol 56 (12) ◽  
pp. 4840-4848 ◽  
Author(s):  
Catinca Secuianu ◽  
Geoffrey C. Maitland ◽  
J. P. Martin Trusler ◽  
William A. Wakeham
Keyword(s):  
Diffusion Coefficients ◽  
High Pressures ◽  
Taylor Dispersion ◽  
Mutual Diffusion ◽  
Dispersion Method ◽  
Taylor Dispersion Method
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