Enthalpy of dilution of aqueous mixtures of amides, sugars, urea, ethylene glycol, and pentaerythritol at 25�C: Enthalpy of interaction of the hydrocarbon, amide, and hydroxyl functional groups in dilute aqueous solutions

1976 ◽  
Vol 5 (10) ◽  
pp. 733-750 ◽  
Author(s):  
James J. Savage ◽  
Robert H. Wood
1975 ◽  
Vol 28 (3) ◽  
pp. 665 ◽  
Author(s):  
C Chan

The solubilities of potassium perrhenate in aqueous NaCl, KCl and KI solutions are reported. The solubility activity product for this electrolyte was determined using extrapolation functions involving three different mean ionic activity coefficient expressions. Mean ionic activity coefficients have been computed for potassium perrhenate in dilute aqueous solutions and there is no justification for considering ion association1,2 in these solutions.


1998 ◽  
Vol 102 (24) ◽  
pp. 4809-4812 ◽  
Author(s):  
Akio Ohta ◽  
Takanori Takiue ◽  
Norihiro Ikeda ◽  
Makoto Aratono

Polymers ◽  
2020 ◽  
Vol 12 (8) ◽  
pp. 1645
Author(s):  
Daria Lipowska-Kur ◽  
Łukasz Otulakowski ◽  
Barbara Trzebicka ◽  
Alicja Utrata-Wesołek ◽  
Andrzej Dworak

A series of copolymers of di(ethylene glycol) methyl ether methacrylate (D) and 2-aminoethyl methacrylate (A) (P(D-co-A)) with variable ratios of comonomers were synthesized using atom transfer radical polymerization. Then, the amino groups of obtained copolymers were modified to clickable azide or prop-2-yn-1-yl carbamate groups. A thermoresponsive copolymers were obtained with the value of cloud point temperature (TCP) dependent on the type and number of functional groups in the copolymer and on the concentration of solutions. For P(D-co-A) copolymers, the TCP increased with increasing content of 2-aminoethyl methacrylate comonomer. The presence of azide and prop-2-yn-1-yl carbamate groups caused the changes of TCP of modified copolymers. All studied copolymers in dilute aqueous solutions aggregated above TCP to nanoparticles with sizes dependent on the solution concentration, heating procedures, and types and numbers of functional groups present in a copolymer chain. The presence of hydrophilic elements in the chain and the increase in the copolymer concentration led to the enlargement of the particle sizes. Aggregates were crosslinked using click reaction between an azide and prop-2-yn-1-yl carbamate groups that led to stable thermoresponsive nanogels. A systematic study of the behavior of copolymers allowed the determination of the chains useful for possible application in drug delivery.


Polymer ◽  
2007 ◽  
Vol 48 (14) ◽  
pp. 4108-4113 ◽  
Author(s):  
Gang Cheng ◽  
Yuri B. Melnichenko ◽  
George D. Wignall ◽  
Fengjun Hua ◽  
Kunlun Hong ◽  
...  

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