Use of impedance measurements for the determination of the instant rate of metal corrosion

1972 ◽  
Vol 2 (1) ◽  
pp. 71-79 ◽  
Author(s):  
I. Epelboin ◽  
M. Keddam ◽  
H. Takenouti
1989 ◽  
Vol 17 (4) ◽  
pp. 360-363 ◽  
Author(s):  
MARIA GRACIA A. ESPEJO ◽  
JOSEF NEU ◽  
LYLE HAMILTON ◽  
BENJAMIN EITZMAN ◽  
PHYLLIS GIMOTTY ◽  
...  

2015 ◽  
Vol 56 (3) ◽  
pp. 315-319
Author(s):  
Biljana Bobić ◽  
Nikola Bajić ◽  
Aleksandar Jegdić ◽  
Maja Stevanović ◽  
Bore Jegdić

1964 ◽  
Vol 17 (7) ◽  
pp. 715 ◽  
Author(s):  
HH Bauer

An equation is derived for the magnitude of the second-harmonic current under ax. polarographic conditions. It is shown that the concentration changes of the depolarizer at the electrode surface do not contain second-harmonic components. The theory permits determination of the rate constant and transfer coefficient, for processes of greater speed than are amenable to elucidation by faradaic-impedance measurements. Furthermore, the major experimental difficulties in faradaic-impedance studies (base current, voltage drop in the series resistances) are virtually absent in second-harmonic work. Second-harmonic studies also promise to be advantageous in the elucidation of adsorption effects in electrochemical reactions.


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