Relation between the luminescence spectra of uranyl salt solutions in organic solvents and the wavelength of the exciting light

1966 ◽  
Vol 4 (4) ◽  
pp. 236-237
Author(s):  
L. V. Volod'ko ◽  
E. A. Turetskaya
Keyword(s):  
Organic Solvents ◽  
Luminescence Spectra ◽  
Exciting Light ◽  
Salt Solutions ◽  
Uranyl Salt

Determination of traces of free acid in uranyl salt solutions

1963 ◽  
Vol 29 ◽  
pp. 22-26 ◽  
Author(s):  
J. Mashall ◽  
A. Bar-Nun
Keyword(s):  
Free Acid ◽  
Salt Solutions ◽  
Uranyl Salt

scholarly journals STUDIES ON CORROSION OF 18-8 STAINLESS STEELS FOR URANYL SALT SOLUTIONS

1957 ◽  
Vol 43 (12) ◽  
pp. 1312-1317 ◽  
Author(s):  
Takashi Kuroyanagi ◽  
Noboru Shinoda ◽  
Ryukiti Hasiguti ◽  
Goro Ito
Keyword(s):  
Stainless Steels ◽  
Salt Solutions ◽  
Uranyl Salt

scholarly journals Особенности спектральных характеристик различных структурных модификаций Lu-=SUB=-1-x-=/SUB=-RE-=SUB=-x-=/SUB=-BO-=SUB=-3-=/SUB=-

2021 ◽  
Vol 63 (10) ◽  
pp. 1617
Author(s):  
С.З. Шмурак ◽  
В.В. Кедров ◽  
А.П. Киселев ◽  
Т.Н. Фурсова ◽  
И.И. Зверькова ◽  
...  
Keyword(s):  
Solid Solution ◽  
Surface Layer ◽  
Structural State ◽  
Spectral Characteristics ◽  
Luminescence Spectra ◽  
Exciting Light ◽  
Ir Absorption ◽  
Two Phase ◽  
Near Surface ◽  
Absorption And Luminescence Spectra

The structure, IR absorption and luminescence spectra of the microcrystals of Lu1-xEuxBO3, Lu0.99-xTbxEu0.01BO3, and Lu0.99−xYxEu0.01BO3 orthoborates (0 ≤ x ≤ 0.25) synthesized at 970°С were studied. An increase in х leads to a sequential change of the structural state of the orthoborates. At х ≤ 0.07 – 0.09, the compounds form a solid solution with the calcite structure and microcrystal size of 8 – 20 µm. Then, they become two-phase: the vaterite phase arises along with the calcite structure. At х ≥ 0.2 – 0.25, the entire bulk of a sample has the vaterite structure. A correspondence between the structure and spectral characteristics of these compounds was established. Luminescence spectra were investigated at different wavelengths of exciting light. This allowed obtaining information on the structure of a near-surface layer and the bulk of microcrystals of the investigated samples. It is shown that the vaterite phase arises both in the bulk of large microsrystals (8 – 20 µm) and in the form of small microsrystals (1 – 2 µm).

scholarly journals Эволюция спектральных и структурных характеристик ортоборатов La-=SUB=-0.98-x-=/SUB=-Lu-=SUB=-x-=/SUB=-Eu-=SUB=-0.02-=/SUB=-BO-=SUB=-3-=/SUB=-

2021 ◽  
Vol 63 (12) ◽  
pp. 2142
Author(s):  
С.З. Шмурак ◽  
В.В. Кедров ◽  
А.П. Киселев ◽  
Т.Н. Фурсова ◽  
И.И. Зверькова ◽  
...  
Keyword(s):  
Surface Layer ◽  
Structural State ◽  
Spectral Characteristics ◽  
Luminescence Spectra ◽  
Exciting Light ◽  
Ir Absorption ◽  
Excitation Spectra ◽  
Two Phase ◽  
Near Surface ◽  
Sequential Change

The structure, IR absorption, luminescence, and luminescence excitation spectra of La0.98xLuxEu0.02 BO3 orthoborates synthesized at 970°C were studied at 0 ≤ x ≤ 0.98. An increase in х leads to a sequential change of the structural state of the orthoborates. At first, the compound has the aragonite structure. Then, it becomes two-phase and contains the aragonite and vaterite phases. With a further increase in х, the compounds have the vaterite structure, then the vaterite and calcite structure, and, finally, the calcite structure. Correspondence between the structure and spectral characteristics of these compounds was established. Luminescence spectra were investigated at different wavelengths of exciting light. This allowed obtaining information on the structure of a near-surface layer and the bulk of microcrystals of the investigated samples. It is shown that the vaterite phase arises in the bulk of microcrystals of samples that have the aragonite structure.

Isomorphous replacement in electron diffraction of wet crystals of rat hemoglobin

1983 ◽  
Vol 41 ◽  
pp. 446-447
Author(s):  
William F. Tivol ◽  
Murray Vernon King ◽  
D. F. Parsons
Keyword(s):  
Electron Diffraction ◽  
Heavy Atom ◽  
Isomorphous Substitution ◽  
X Ray Diffraction ◽  
Salt Solutions ◽  
X Ray ◽  
Isomorphous Replacement ◽  
Structure Factors ◽  
Diffraction Structure ◽  
The Mean

Feasibility of isomorphous substitution in electron diffraction is supported by a calculation of the mean alteration of the electron-diffraction structure factors for hemoglobin crystals caused by substituting two mercury atoms per molecule, following Green, Ingram & Perutz, but with allowance for the proportionality of f to Z3/4 for electron diffraction. This yields a mean net change in F of 12.5%, as contrasted with 22.8% for x-ray diffraction.Use of the hydration chamber in electron diffraction opens prospects for examining many proteins that yield only very thin crystals not suitable for x-ray diffraction. Examination in the wet state avoids treatments that could cause translocation of the heavy-atom labels or distortion of the crystal. Combined with low-fluence techniques, it enables study of the protein in a state as close to native as possible.We have undertaken a study of crystals of rat hemoglobin by electron diffraction in the wet state. Rat hemoglobin offers a certain advantage for hydration-chamber work over other hemoglobins in that it can be crystallized from distilled water instead of salt solutions.

Bulk standards for low-temperature biological x-ray microanalysis

1984 ◽  
Vol 42 ◽  
pp. 282-283
Author(s):  
P. Echlin ◽  
M. McKoon ◽  
E.S. Taylor ◽  
C.E. Thomas ◽  
K.L. Maloney ◽  
...  
Keyword(s):  
Phase Separation ◽  
Low Temperature ◽  
Analytical Method ◽  
Salt Solutions ◽  
Absolute Concentration ◽  
Cooling Process ◽  
X Ray ◽  
The Absolute ◽  
Analytical Procedures ◽  
Electrical Conductors

Although sections of frozen salt solutions have been used as standards for x-ray microanalysis, such solutions are less useful when analysed in the bulk form. They are poor thermal and electrical conductors and severe phase separation occurs during the cooling process. Following a suggestion by Whitecross et al we have made up a series of salt solutions containing a small amount of graphite to improve the sample conductivity. In addition, we have incorporated a polymer to ensure the formation of microcrystalline ice and a consequent homogenity of salt dispersion within the frozen matrix. The mixtures have been used to standardize the analytical procedures applied to frozen hydrated bulk specimens based on the peak/background analytical method and to measure the absolute concentration of elements in developing roots.

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