The electronic and IR spectra of a symmetrical macroheterocyclic compound containing 1, 3, 4-thiadiazole rings, and of its copper complex

1971 ◽  
Vol 14 (6) ◽  
pp. 828-830
Author(s):  
N. A. Kolesnikov ◽  
V. F. Borodkin
Keyword(s):  
Ir Spectra ◽  
Copper Complex ◽  
Macroheterocyclic Compound

Visualization of ultrasonic cavitation in visible and IR spectra

2010 ◽  
Author(s):  
A. Osterman ◽  
O. Coutier-Delgosha ◽  
M. Hocevar ◽  
B. Sirok
Keyword(s):  
Ir Spectra ◽  
Ultrasonic Cavitation

Light- or Dark-Colored, L-DOPA-Based Melanins

2018 ◽  
Author(s):  
Koen Vercruysse ◽  
Margaret M. Whalen
Keyword(s):  
Human Physiology ◽  
Ir Spectra ◽  
Immune Cells ◽  
Chemical Properties ◽  
Chemical Signature ◽  
Ft Ir

<p>This report is a continuation of previous research on the H<sub>2</sub>O<sub>2</sub>-mediated synthesis of melanin-like pigments. We synthesized and characterized L-DOPA-based pigments using air- or H<sub>2</sub>O<sub>2</sub>-mediated<sub> </sub>oxidation. We compared their physic-chemical properties and evaluated their capacity to affect the interleukin release from immune cells. The use of higher concentrations of H<sub>2</sub>O<sub>2</sub> resulted in melanin-like materials with a distinct chemical signature in their FT-IR spectra and a lighter color. All pigments enhanced the interleukin release from immune cells. The possibility that lighter-colored melanins can be generated is discussed in the context of the importance of melanin-based pigmentation in human physiology.</p>

Tetranuclear Copper and Mononuclear Nickel Complex of the Schiff Base of (3Z)-3-Hydrazonobutan-2-One Oxime with Different Aromatic Carbonyl Compounds: Synthesis, Single Crystal X-Ray Structure, Catecholase Activity, Phenoxazinone Synthase Activity, Catalytic Study for the Homocoupling of Benzyl Amines

2019 ◽  
Author(s):  
Swaraj Sengupta ◽  
Sahanwaj Khan ◽  
Shyamal K. Chattopadhyay ◽  
Indrani Banerjee ◽  
Tarun K. Panda ◽  
...  
Keyword(s):  
Schiff Base ◽  
Single Crystal ◽  
Copper Complex ◽  
Carbonyl Compounds ◽  
Nickel Complex ◽  
Schiff Base Ligands ◽  
X Ray ◽  
Phenoxazinone Synthase ◽  
Catecholase Activity ◽  
Aromatic Carbonyl Compounds

Synthesis and characterisation of one trinuclear copper complex, ([Cu<sub>3</sub>L<sub>3</sub>O]ClO<sub>4</sub>) (<b>1</b>) and one nickel complex ([Ni(L'H)<sub>2</sub>(dmso)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub>) (<b>2</b>) with Schiff base ligands: (3Z)-3-((Z)-(1-(thiophen-2-yl)ethylidene)hydrazono)butan-2-one oxime (LH) and 1-(pyridin-2-yl)ethylidene)hydrazono)butan-2-one oxime (L<sup>'</sup>H). <b>1</b> shows high catecholase activity and has also been tested as a catalyst for the synthesis of benzylimine. <b>2 </b> shows phenoxazinone synthase activity.

Sulphoamidic Phtalocyaninic Pigments and Dyes(II)

2008 ◽  
Vol 59 (5) ◽  
Author(s):  
Elena Stingaciu ◽  
Corneliu Minca ◽  
Ion Sebe
Keyword(s):  
Ir Spectra ◽  
Aromatic Amines ◽  
Free Groups ◽  
Cyanuric Chloride ◽  
Layer Chromatography ◽  
Phenylene Diamine

This work concerns the synthesis of pigments and phtalocyanine dyes obtained through the sulphonation of copper phtalocyanine and amidation with some aliphatic and aromatic amines (lauryl-amine, i-propyl-amine, hexadecyl-amine, stearyl-amine and acetyl-p-phenylene-diamine) with good properties for the electrotechnic utilisation and for toner materials. The pigments with amino free groups are transformed by condensation with cyanuric chloride in phtalocyanine pigments with different tinctorial properties. The dyes were analyzed through the layer chromatography and were characterized on the IR spectra bases and tinctorial tests.

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