Effects of sample composition and dispersion on spectral analysis by blowing into an arc plasma

1971 ◽  
Vol 14 (6) ◽  
pp. 703-706
Author(s):  
A. K. Rusanov ◽  
L. I. Serdobova
Keyword(s):  
Spectral Analysis ◽  
Arc Plasma ◽  
Sample Composition

Plasma parameters in atomic-emission spectral analysis of phosphate concentrates of the fission products

2019 ◽  
Vol 85 (2) ◽  
pp. 17-22
Author(s):  
M. I. Khamdeev ◽  
E. A. Erin
Keyword(s):  
Spectral Analysis ◽  
Chemical Composition ◽  
Reference Materials ◽  
Fission Products ◽  
Atomic Emission ◽  
Electric Arc ◽  
Physical Parameters ◽  
Arc Plasma ◽  
Atomic Emission Spectral Analysis ◽  
Excitation Processes

Physical parameters of electric arc plasma as well as their time dependences are calculated when analyzing phosphate precipitates of the fission products of irradiated nuclear fuel. Phosphate concentrates of the fission products are known for their complex chemical composition and high thermal and chemical stability. Hence, direct atomic emission spectral analysis of phosphate powders without transferring them into solutions is advisable. Different conditions of sample preparation and synthesis of the reference materials determine the different chemical forms of the elements to be determined. This, in turn, affects the kinetics of their evaporation in the electrode crate and excitation processes in the plasma. The known mechanisms of those processes cannot always be transferred to specific conditions of the given method of analysis thus entailing the necessity of studying the effect of the samples chemical composition on the results of determination, proper choice of spectroscopic carriers, detailed study of spectra excitation processes in spectral analysis, and analysis of the physical parameters of the electric arc plasma. We used the lines Zn I 307.206 nm and Zn I 307.589 nm to measure the effective temperature of the central hot sections of the arc in a range of4500 - 6500 K. NaCl, BaCl2 and NaCl + T1C1 were studied to reduce the effect of the sample elemental composition on excitation conditions of the spectra and their stabilization as a spectroscopic carrier. In control experiments we used carrier-free samples. The coincidence of the values of the plasma physical parameters within the measurement error not exceeding 20%, as well as the identity of the nature of the kinetic curves for samples of phosphate precipitates and synthetic reference materials prove their correctness. The result of the study substantiate correctness of the direct atomic-emission spectral procedure in analysis of phosphate concentrates of fission when using synthetic reference materials.

Isotopic Chromatographic Spectral Analysis of Inorganic Gases

1994 ◽  
Vol 48 (7) ◽  
pp. 884-890 ◽  
Author(s):  
Valery N. Funtov ◽  
Valeriy M. Nemets ◽  
Arcadiy A. Petrov ◽  
Anatoliy A. Soloviov
Keyword(s):  
Spectral Analysis ◽  
Total Content ◽  
High Sensitivity ◽  
Gas Analysis ◽  
Molecular Compound ◽  
Individual Element ◽  
Sample Composition ◽  
The Individual ◽  
Chromatographic Isolation ◽  
Reference Samples

The possibilities of the hyphenated isotopic chromatographic spectral method (ICSM) of inorganic gas analysis are considered. The technique allows detection of both the individual element and molecular admixtures. For evaluation of the total content of the element, isotope balancing and conversion of all components containing this element into a molecular compound more suitable for chromatographic isolation and spectroscopic detection are used. High sensitivity is achieved by preconcentration of admixtures with the simultaneous monitoring of possible distortions of the sample composition at all stages of analysis by means of the introduction of a rare stable isotope. The fields of application are the analysis of high-purity gases, evaluation of the total contents of individual elements, metrological tasks of apparatus calibration, and so on. The method does not need reference samples prepared from the analyzed gaseous matrices for the calibration itself.

Emission Spectral Analysis of Arc Plasma on Solar Array in GEO Environment

2006 ◽  
Author(s):  
Takayuki Ose ◽  
Yuya Sanmaru ◽  
Tomoki Kitamura ◽  
Satoshi Hosoda ◽  
Kazuhiro Toyoda ◽  
...  
Keyword(s):  
Spectral Analysis ◽  
Emission Spectral Analysis ◽  
Solar Array ◽  
Arc Plasma

Spectral analysis of asymmetry training effect for depression

2008 ◽  
Author(s):  
Ji Ha Lee ◽  
Sung Won Choi ◽  
Ji Sun Min ◽  
Eun Ju Jaekal ◽  
Gyhye Sung
Keyword(s):  
Spectral Analysis ◽  
Training Effect

Some problems in the spectral analysis of human behavior records

1953 ◽  
Author(s):  
C. J. Burke ◽  
R. Narasimhan ◽  
O. J. Benepe
Keyword(s):  
Spectral Analysis ◽  
Human Behavior
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