Acoustic microscopy and XPS-analysis of the polymer/metal-interface of adhesive joints and coatings

1989 ◽  
Vol 333 (4-5) ◽  
pp. 346-349 ◽  
Author(s):  
J. v. Czarnecki ◽  
A. Müller ◽  
O. Rist
Keyword(s):  
Adhesive Joints ◽  
Acoustic Microscopy ◽  
Xps Analysis ◽  
Metal Interface ◽  
Polymer Metal

The Competition between Adhesive and Cohesive Fracture at Amicro-Patterned Polymer-Metal Interface

2013 ◽  
Vol 577-578 ◽  
pp. 225-228 ◽  
Author(s):  
Olaf van der Sluis ◽  
Joris J.C. Remmers ◽  
M.A.C. Thurlings ◽  
B.J. Welling ◽  
Sander P.M. Noijen
Keyword(s):  
Crack Deflection ◽  
Surface Roughening ◽  
Adhesive Failure ◽  
Cohesive Failure ◽  
Metal Interface ◽  
Cohesive Fracture ◽  
Micro Patterning ◽  
Polymer Metal ◽  
Metal Interfaces ◽  
Point Bend

It is Common Practice for Polymer-Metal Interfaces, Frequently Encountered in Microelec-Tronic Devices, to Improve Adhesion by Surface Roughening or Micro-Patterning. the Competitionbetween Adhesive Fracture and Cohesive Fracture in the Vicinity of a Patterned Interface, i.e., Inter-Face Crack Deflection, is One of these Key Mechanisms that Contribute Significantly to the Macroscopicadhesion. in this Paper, these Fracture Phenomena are Described Simultaneously by Cohesive Zoneelements with an Exponential Traction-Separation Law (TSL) for the Adhesive Failure and an Initiallyrigid, Exponentially Decaying, TSL for the Cohesive Failure. it is Demonstrated that the Conditions Atwhich Crack Kinking Occurs are Dominated by Fracture Strength Values as Opposed to the Commonlyused Fracture Toughness Values. Experimental Verification is Performed by Means of Four Point Bend-Ing Tests on Specifically Designed Micro-Patterned Polymer-Metal Samples.

Piezoelectric actuation of factigue crack growth along polymer/metal interface

2001 ◽  
pp. 187-192
Author(s):  
T. Du ◽  
M. Liu ◽  
S. Seghi ◽  
K.J. Hsia ◽  
J. Economy ◽  
...  
Keyword(s):  
Crack Growth ◽  
Piezoelectric Actuation ◽  
Metal Interface ◽  
Polymer Metal

An Engineering Model for Moisture Degradation of Polymer/Metal Interfacial Fracture Toughness

2005 ◽  
Author(s):  
Timothy P. Ferguson ◽  
Jianmin Qu
Keyword(s):  
Fracture Toughness ◽  
Fracture Mechanics ◽  
Interfacial Fracture ◽  
Interfacial Fracture Toughness ◽  
Engineering Model ◽  
Metal Interface ◽  
Moisture Concentration ◽  
Interfacial Fracture Mechanics ◽  
Polymer Metal

Based on interfacial fracture mechanics and the hydrophobicity of the interface, en engineering model was developed in this paper. Using this model, one can predicted the degradation of interfacial fracture toughness of a polymer/metal interface once the moisture concentration near the interface is known.

Diffusion of Cations Along the Polymer/Metal Interface Under an Applied Electrical Potential

1993 ◽  
Vol 304 ◽  
Author(s):  
T. Nguyen ◽  
J. M. Pommersheim
Keyword(s):  
Experimental Data ◽  
Moving Boundary ◽  
Electrical Potential ◽  
Potential Gradient ◽  
Polymer Coatings ◽  
Diffusion Problem ◽  
Model Parameters ◽  
Metal Interface ◽  
Problem Model ◽  
Polymer Metal

AbstractDiffusion of cations along the polymer/metal interface controls the rate of blistering of polymer coatings on metals exposed to electrolytes. Cations are driven by both concentration and electrical potential gradients. A theoretical and experimental study was carried out on the diffusion of sodium ion along the polymer coating/steel interface under an applied potential. Mathematical models, consisting of initial and propagation stages, are derived based on a moving boundary diffusion problem. Model variables include ion diffusivity, potential gradient and distance between defects and delamination sites. Models are solved to predict ion fluxes and concentration in the blistering areas. Experimental data are analyzed to extract model parameters. Model predictions agreed well with experimental data and practical observations

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