Bond orbital approach for optical rotatory strength calculations

1983 ◽  
Vol 63 (1) ◽  
pp. 43-54 ◽  
Author(s):  
J�nos �ngy�n ◽  
P�ter R. Surj�n
Keyword(s):  
Optical Rotatory ◽  
Optical Rotatory Strength

Chiroptical properties of monosaccharide acetyl derivatives

1985 ◽  
Vol 50 (3) ◽  
pp. 683-689
Author(s):  
Slavomír Bystrický ◽  
Tibor Sticzay ◽  
Štefan Kučár ◽  
Eva Petráková ◽  
Rudolf Toman
Keyword(s):  
Circular Dichroism ◽  
Dipole Moments ◽  
Spatial Arrangement ◽  
Positional Isomers ◽  
Optical Rotatory ◽  
Chiroptical Properties ◽  
Rotational Strength ◽  
Circular Dichroïsm ◽  
Optical Rotatory Strength

Circular dichroism of positional isomers of acetylated methyl β-D-xylopyranosides, 1,6-anhydro-β-D-glucopyranoses and methyl α-L-rhamnopyranosides is discussed considering the mechanism of optical rotatory strength nature. Interactions determining the signs are influenced by the character of the solvent. Magnitude of the effect depends on the spatial arrangement of the chromophore environment. This effect is lowered with diacetyl derivatives, where the interaction of transitional dipole moments of acetyl groups is the main source of optical rotational strength.

Optical rotatory strength of tris-bidentate cobalt(III) complexes

1974 ◽  
Vol 13 (4) ◽  
pp. 945-950 ◽  
Author(s):  
R. R. Judkins ◽  
D. J. Royer
Keyword(s):  
Optical Rotatory ◽  
Optical Rotatory Strength
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