The reaction processes of soda cellulose with carbon disulphide

1972 ◽  
Vol 3 (5) ◽  
pp. 488-497 ◽  
Author(s):  
H. Dautzenberg ◽  
B. Philipp
Keyword(s):  
Carbon Disulphide ◽  
Soda Cellulose ◽  
Reaction Processes

The Liquefaction of Oxygen and the Solidification of Carbon Disulphide and Alcohol

1883 ◽  
Vol 16 (416supp) ◽  
pp. 6641-6641
Author(s):  
S. V. Wroblewski ◽  
K Olszewski
Keyword(s):  
Carbon Disulphide

Lifetime Prediction of Tires with Regard to Oxidative Aging5

2008 ◽  
Vol 36 (1) ◽  
pp. 63-79 ◽  
Author(s):  
L. Nasdala ◽  
Y. Wei ◽  
H. Rothert ◽  
M. Kaliske
Keyword(s):  
Finite Element Analysis ◽  
Finite Element ◽  
Temperature Distribution ◽  
Superposition Principle ◽  
Accelerated Aging ◽  
Material Model ◽  
Aging Behavior ◽  
Element Analysis ◽  
Material Parameters ◽  
Reaction Processes

Abstract It is a challenging task in the design of automobile tires to predict lifetime and performance on the basis of numerical simulations. Several factors have to be taken into account to correctly estimate the aging behavior. This paper focuses on oxygen reaction processes which, apart from mechanical and thermal aspects, effect the tire durability. The material parameters needed to describe the temperature-dependent oxygen diffusion and reaction processes are derived by means of the time–temperature–superposition principle from modulus profiling tests. These experiments are designed to examine the diffusion-limited oxidation (DLO) effect which occurs when accelerated aging tests are performed. For the cord-reinforced rubber composites, homogenization techniques are adopted to obtain effective material parameters (diffusivities and reaction constants). The selection and arrangement of rubber components influence the temperature distribution and the oxygen penetration depth which impact tire durability. The goal of this paper is to establish a finite element analysis based criterion to predict lifetime with respect to oxidative aging. The finite element analysis is carried out in three stages. First the heat generation rate distribution is calculated using a viscoelastic material model. Then the temperature distribution can be determined. In the third step we evaluate the oxygen distribution or rather the oxygen consumption rate, which is a measure for the tire lifetime. Thus, the aging behavior of different kinds of tires can be compared. Numerical examples show how diffusivities, reaction coefficients, and temperature influence the durability of different tire parts. It is found that due to the DLO effect, some interior parts may age slower even if the temperature is increased.

Flame ionization detector response to coeluting hydrocarbons and carbon disulphide and its application to the determination of the sum of C6-C11 alkanes and cycloalkanes in air

1983 ◽  
Vol 48 (3) ◽  
pp. 722-734
Author(s):  
Martin Koval
Keyword(s):  
Carbon Disulphide ◽  
Internal Standard ◽  
Calibration Procedure ◽  
Detector Response ◽  
Column Temperature ◽  
Flame Ionization ◽  
Other Substances ◽  
Flame Ionisation Detector ◽  
Ionisation Detector

The flame ionisation detector response to C6-C11 aliphatic hydrocarbon solutions in carbon disulphide in the concentration range between 1.3-9.5 mg ml-1 retained lineary despite the excess of solvent entering the detector simultaneously with the analyte. Pure carbon disulphide exhibited a small positive detector response which did not interfere in calibration procedure and which, under certain GC conditions, inverted to negative values. This response was not proportional to the injected volume and was strongly influenced by the column temperature and/or bleed. On the basis of these findings, a method compatible with the widely used charcoal tube carbon disulphide desorption procedure was developed and evaluated. It consists of static desorption of the sum of aliphatic alkanes and cycloalkanes from the activated charcoal after which an internal standard is added to the supernatant eluate. The resulting carbon disulphide solution is analysed on a highly polar stationary phase 1,2,3-tris(2-cyanoethoxy)propane where the solvent and the analyte coelute in a single peak, the height of which is practically proportional to the sum of alkanes and cycloalkanes present. This also makes determinations of other substances present in the sample more simple. The field test of the proposed method yielded values comparable in precision and accuracy with a control infrared spectrophotometric method.

Study on the precision of the activated charcoal solvent desorption procedure - Correlation of desorption efficiencies

1981 ◽  
Vol 46 (6) ◽  
pp. 1332-1347 ◽  
Author(s):  
Martin Koval
Keyword(s):  
Activated Charcoal ◽  
Carbon Disulphide ◽  
Internal Standard ◽  
Standard Addition ◽  
Published Data ◽  
Single Factor ◽  
Gas Chromatograph ◽  
Model Compounds ◽  
Single Factor Analysis ◽  
Acceptable Agreement

The described method uses activated charcoal sampling tubes for air sampling. Adsorbed compounds are eluted by the static desorption procedure with 1 ml of carbon disulphide, 0.5 ml of the supernatant is filtered off and, after internal standard addition, analysed on a gas chromatograph. Using synthetic calibration mixtures of model organic compounds with air, cumulative sampling and desorption efficiencies for 24 substances were determined for concentration ranges and sample volumes according to current Czechoslovak hygienic standards. Experimental results were treated with the single factor analysis of variance and the precision of the described procedure was estimated for the studied model compounds on the basis of residual sums of squares. Calculated values of cumulative sampling and desorption efficiencies and their precisions were compared with available published data and an acceptable agreement was found. In addition to that, cumulative sampling and desorption efficiencies were also found to be significantly correlated to molar volumes and other related molecular properties for some types of compounds.

Effects of Mn2+, Ni2+, and Cu2+ on the Formation and Transformation of Hydrosulfate Green Rust: Reaction Processes and Underlying Mechanisms

2019 ◽  
Vol 3 (4) ◽  
pp. 519-530 ◽  
Author(s):  
Xiaoming Wang ◽  
Jing Peng ◽  
Xiaoliang Liang ◽  
Mengqiang Zhu ◽  
Bruno Lanson ◽  
...  
Keyword(s):  
Green Rust ◽  
Underlying Mechanisms ◽  
Reaction Processes

scholarly journals Morphology Controlled Synthesis of γ-Al2O3 Nano-Crystallites in Al@Al2O3 Core–Shell Micro-Architectures by Interfacial Hydrothermal Reactions of Al Metal Substrates

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 310
Author(s):  
Dohyeon Han ◽  
Doohwan Lee
Keyword(s):  
Electrostatic Interactions ◽  
Heterogeneous Catalysts ◽  
Metal Substrate ◽  
Inorganic Anions ◽  
Core Shell ◽  
Hydroxyl Groups ◽  
Hydrothermal Reactions ◽  
Fine Control ◽  
Reaction Processes

Fine control of morphology and exposed crystal facets of porous γ-Al2O3 is of significant importance in many application areas such as functional nanomaterials and heterogeneous catalysts. Herein, a morphology controlled in situ synthesis of Al@Al2O3 core–shell architecture consisting of an Al metal core and a porous γ-Al2O3 shell is explored based on interfacial hydrothermal reactions of an Al metal substrate in aqueous solutions of inorganic anions. It was found that the morphology and structure of boehmite (γ-AlOOH) nano-crystallites grown at the Al-metal/solution interface exhibit significant dependence on temperature, type of inorganic anions (Cl−, NO3−, and SO42−), and acid–base environment of the synthesis solution. Different extents of the electrostatic interactions between the protonated hydroxyl groups on (010) and (001) facets of γ-AlOOH and the inorganic anions (Cl−, NO3−, SO42−) appear to result in the preferential growth of γ-AlOOH toward specific crystallographic directions due to the selective capping of the facets by adsorption of the anions. It is hypothesized that the unique Al@Al2O3 core–shell architecture with controlled morphology and exposed crystal-facets of the γ-Al2O3 shell can provide significant intrinsic catalytic properties with enhanced heat and mass transport to heterogeneous catalysts for applications in many thermochemical reaction processes. The direct fabrication of γ-Al2O3 nano-crystallites from Al metal substrate with in-situ modulation of their morphologies and structures into 1D, 2D, and 3D nano-architectures explored in this work is unique and can offer significant opportunities over the conventional methods.

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