Kinetics of densification during hot-pressing of aluminium nitride

1981 ◽  
Vol 16 (11) ◽  
pp. 3093-3098 ◽  
Author(s):  
J. -P. Lecompte ◽  
J. Jarrige ◽  
J. Mexmain ◽  
R. J. Brook ◽  
F. L. Riley
1982 ◽  
Vol 17 (10) ◽  
pp. 3072-3074 ◽  
Author(s):  
W. H. Gourdin ◽  
L. E. Tanner

1983 ◽  
pp. 293-299 ◽  
Author(s):  
J.P. Lecompte ◽  
J. Jarrige ◽  
J. Mexmain

2010 ◽  
Vol 636-637 ◽  
pp. 605-611 ◽  
Author(s):  
Rene Radis ◽  
Ernst Kozeschnik

In this work, the thermodynamic information on aluminium nitride formation and experimental precipitation kinetics data are reviewed. A revised expression for the Gibbs energy of AlN is developed with special emphasis on microalloyed steel. Using the software package MatCalc, computer simulations of AlN precipitation kinetics are performed and compared to several independent experimental results from literature. To mimic the geometrical arrangement of AlN precipitates along austenite grain boundaries, a new model for precipitation at grain boundaries is used, which takes into account fast short-circuit diffusion along grain boundaries as well as the slower bulk diffusion of atoms from inside the grain to the grain boundaries. This is essential for the calculation of AlN precipitation in austenite where nucleation occurs predominantly on grain boundaries. By studying the AlN precipitation at grain boundaries numerically, and by comparison with experimental data, it is demonstrated that the precipitation kinetics of AlN differs significantly from the simulated precipitation kinetics of randomly distributed precipitates assuming spherical diffusion fields.


1972 ◽  
Vol 11 (1) ◽  
pp. 22-27
Author(s):  
D. M. Karpinos ◽  
L. I. Tuchinskii ◽  
V. Ya. Fefer

1987 ◽  
Vol 26 (11) ◽  
pp. 881-884 ◽  
Author(s):  
M. S. Koval'chenko ◽  
Yu. G. Tkachenko ◽  
L. F. Ochkas ◽  
D. Z. Yurchenko ◽  
V. B. Vinokurov

1980 ◽  
Vol 15 (12) ◽  
pp. 3017-3024 ◽  
Author(s):  
M. P. Harmer ◽  
R. J. Brook
Keyword(s):  

1996 ◽  
Vol 35 (1-2) ◽  
pp. 25-31 ◽  
Author(s):  
A. I. Kharlamov ◽  
N. V. Kirillova ◽  
S. V. Loichenko
Keyword(s):  

Holzforschung ◽  
2010 ◽  
Vol 64 (5) ◽  
Author(s):  
Yi Wang ◽  
Vikram Yadama ◽  
Marie-Pierre Laborie ◽  
Debes Bhattacharyya

Abstract In thermoforming of profiled wood-strand composites, an adhesive system is needed to provide a weak initial bond to maintain mat integrity and architecture during the forming process and eventually a durable bond when the final cross-sectional shape is achieved. A hybrid adhesive composed of phenol formaldehyde (PF) and poly(vinyl acetate) (PVAc) is proposed in this study. The cure kinetics of this hybrid adhesive and bond development in a multi-step hot-pressing is discussed. Cure kinetics studied by differential scanning calorimetry indicated that adding PVAc slowed down the curing reaction of PF resin; however, the full cure of PF was not inhibited. The nth-order Borchardt Daniels (nth-BD) model provided good prediction for the curing of adhesives with a PF/PVAc ratio lower than 1:1. To simulate roll forming of wood-strand mats, a hot-pressing schedule at low temperature combined with multi-stage closing and opening was developed. The nth-BD model was able to predict the actual bond development for composites made with neat PF resin. The results indicated that cure kinetics of a PF/PVAc hybrid adhesive would not significantly differ from neat PF resin for blend ratios of 1:1 or lower, thus potentially providing a resin system for roll forming or matched-die forming of wood-strand composites.


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