A study of the kinetics of the exchange reaction between two complexes using the method of graphs

1973 ◽  
Vol 6 (5) ◽  
pp. 523-530
Author(s):  
T. A. Rumyantseva ◽  
L. I. Budarin ◽  
K. B. Yatsimirskii
Keyword(s):  
Exchange Reaction ◽  
Kinetics Of

Kinetics of the exchange reaction between 1,10-phenanthroline and triethylenetetraminenickel(II)

1972 ◽  
Vol 11 (7) ◽  
pp. 1505-1510 ◽  
Author(s):  
R. K. Steinhaus ◽  
J. A. Boersma
Keyword(s):  
Exchange Reaction ◽  
Kinetics Of

Kinetics of radical exchange in the reaction of CF3 radicals with tin tetramethyl

1976 ◽  
Vol 54 (10) ◽  
pp. 1617-1623 ◽  
Author(s):  
T. N. Bell ◽  
P. J. Young
Keyword(s):  
Exchange Reaction ◽  
Rate Constant ◽  
Additional Data ◽  
Hydrogen Abstraction ◽  
Arrhenius Parameters ◽  
Abstraction Reaction ◽  
Reaction Proceeds ◽  
Kinetics Of

The reaction of CF3 radicals with SnMe4 leads to hydrogen abstraction and also radical exchange.[Formula: see text]We propose the exchange reaction proceeds via a five coordinate intermediate. The Arrhenius parameters for the exchange reaction are,[Formula: see text]Additional data for the H abstraction reaction[Formula: see text]combined with previous data yields an improved rate constant for abstraction,[Formula: see text]

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