Region of multiplicity of stationary states in the oxidation of carbon monoxide over platinum

1981 ◽  
Vol 16 (4) ◽  
pp. 375-379 ◽  
Author(s):  
V. I. Bykov ◽  
Yu. G. Zarkhin ◽  
G. S. Yablonskii
Keyword(s):  
Carbon Monoxide ◽  
Stationary States ◽  
Oxidation Of Carbon Monoxide

Oscillations, glow and ignition in carbon monoxide oxidation in an open system. I. Experimental studies of the ignition diagram and the effects of added hydrogen

1985 ◽  
Vol 397 (1812) ◽  
pp. 21-44 ◽  
Keyword(s):  
Carbon Monoxide ◽  
Open System ◽  
Reaction Rate ◽  
Experimental Studies ◽  
Reaction Rates ◽  
Step Change ◽  
Stable Node ◽  
Stationary States ◽  
Show Evidence ◽  
Oxidation Of Carbon Monoxide

The oxidation of carbon monoxide in equimolar mixtures (CO + O 2 ) has been studied in a well-stirred open system (0.5 dm 3 ) at vessel temperatures in the range 700-840 K, and reactant pressures up to 100 Torr ( ca . 13.3 kPa) at a mean residence time of 8.5 s. Stationary states are established and oscillatory states sustained indefinitely in this system. The effect of small quantities of added hydrogen is studied by a carefully controlled, continuous supplement to the principal reactants. Four different modes of reaction (I-IV) have been characterized, and conditions for their occurrence mapped on a reactant pressure-vessel temperature ( p - T a ) ignition diagram. Most boundaries are quite sharp, and some show evidence of hysteresis. Close to the axes, reaction is slow, non-luminous and non-oscillatory (I). Within a first broad promontory (II) reaction is accompanied by steady luminescence. Crossing the boundary is not accompanied by a step change in reaction rate, but there is a change in character from stable node (in I) to stable focus (in II). Auto-oscillatory luminescence occurs in a closed region (III) wholly within the promontory II. The effects of adding hydrogen on all these modes is to increase the reaction rates markedly and to make them non-isothermal; the boundaries between I, II and III are not as greatly affected. However, systems to which more than 0.10% H 2 have been added also display a new mode, of oscillatory ignition. This appears at first in a region (IV) of high temperatures and pressures but as more H 2 is increased its realm expands and it eventually dominates the ignition diagram, invading the region of luminescence and soon obliterating the oscillatory part completely.

Support and Gas Environment Effects on the Preferential Oxidation of Carbon Monoxide over Co3O4 Catalysts Studied in situ

2021 ◽  
pp. 120450
Author(s):  
Thulani M. Nyathi ◽  
Mohamed I. Fadlalla ◽  
Nico Fischer ◽  
Andrew P.E. York ◽  
Ezra J. Olivier ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Preferential Oxidation ◽  
Environment Effects ◽  
Gas Environment ◽  
Oxidation Of Carbon Monoxide

Oxidation of carbon monoxide and formic acid on bulk and nanosized Pt–Co alloys

2011 ◽  
Vol 16 (2) ◽  
pp. 587-595 ◽  
Author(s):  
Maja D. Obradović ◽  
Amalija V. Tripković ◽  
Snežana Lj. Gojković
Keyword(s):  
Carbon Monoxide ◽  
Formic Acid ◽  
Co Alloys ◽  
Oxidation Of Carbon Monoxide
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