Kinetics of exhaustive oxidation of small quantities of aromatic hydrocarbons

1983 ◽  
Vol 19 (2) ◽  
pp. 158-166
Author(s):  
A. S. Drykhlov ◽  
N. N. Golubeva ◽  
S. L. Kiperman
Keyword(s):  
Aromatic Hydrocarbons ◽  
Exhaustive Oxidation ◽  
Kinetics Of

scholarly journals The combustion of aromatic and alicyclic hydrocarbons. II. The ignition of aromatic hydrocarbons at high temperatures

1939 ◽  
Vol 171 (946) ◽  
pp. 421-433 ◽  
Keyword(s):  
High Temperatures ◽  
Aromatic Hydrocarbons ◽  
Isothermal Oxidation ◽  
Present Communication ◽  
Temperature Range ◽  
Benzene Toluene ◽  
The Subject ◽  
Kinetics Of

In the first paper of this series (Burgoyne 1937) the kinetics of the isothermal oxidation above 400° C of several aromatic hydrocarbons was studied. The present communication extends this work to include the phenomena of ignition in the same temperature range, whilst the corresponding reactions below 400° C form the subject of further investigations now in progress. The hydrocarbons at present under consideration are benzene, toluene, ethylbenzene, n -propylbenzene, o-, m - and p -xylenes and mesitylene.

Oxidation kinetics of polycyclic aromatic hydrocarbons by permanganate

Chemosphere ◽  
2010 ◽  
Vol 79 (6) ◽  
pp. 628-636 ◽  
Author(s):  
Steven P. Forsey ◽  
Neil R. Thomson ◽  
James F. Barker
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Aromatic Hydrocarbons ◽  
Oxidation Kinetics ◽  
Polycyclic Aromatic ◽  
Kinetics Of

scholarly journals Unusually sluggish microemulsion system with water, toluene and a technical branched alkyl polyethoxylate

2015 ◽  
Vol 21 (3) ◽  
pp. 429-439 ◽  
Author(s):  
Marija Ilic ◽  
Franz-Hubert Haegel ◽  
Vesna Pavelkic ◽  
Snezana Zlatanovic ◽  
Zoran Markovic ◽  
...  
Keyword(s):  
Aromatic Hydrocarbons ◽  
Nonionic Surfactants ◽  
Binary Phase Diagram ◽  
Visual Observation ◽  
Ternary Mixtures ◽  
Microemulsion System ◽  
Slow Kinetics ◽  
Bicontinuous Microemulsion ◽  
Kinetics Of ◽  
Qualitative Measurements

Microemulsion systems with water, toluene and nonionic surfactants are interesting for application due to the excellent solvent properties of aromatic hydrocarbons. In this study, the pseudo-binary phase diagram (?fish-diagram?) of such a ternary system was investigated using a branched technical alkyl polyethoxylate. Lutensol ON 50 (i-C10E5) was considered a suitable surfactant. The system with technical branched i-C10E5 exhibits very long and for compositions near optimum solubilization, i.e. the minimum content of surfactant needed for a bicontinuous microemulsion, extremely long times for equilibration. In addition to visual observation, qualitative measurements of turbidity were performed with a UV-Vis spectrometer for characterizing the behavior of this unusually sluggish system. Isothermal phase diagrams at 20, 25 and 30?C yielded inconsistent results after the change of temperature and the application of mechanical stress for different treatment of the samples. Ternary mixtures of water, toluene, and Lutensol ON 50 seem to form long-living metastable states. The sluggishness and the ambiguous phase behavior of the system are discussed. Inconsistent results are attributed to the slow kinetics of the formation and destruction of liquid crystals and the ability of the system to form miniemulsions within an unusual concentration range.

Electronic structure-based rate rules for Ḣ ipso addition–elimination reactions on mono-aromatic hydrocarbons with single and double OH/CH3/OCH3/CHO/C2H5 substituents: a systematic theoretical investigation

2020 ◽  
Vol 22 (36) ◽  
pp. 20368-20387
Author(s):  
Luna Pratali Maffei ◽  
Tiziano Faravelli ◽  
Carlo Cavallotti ◽  
Matteo Pelucchi
Keyword(s):  
Electronic Structure ◽  
Theoretical Investigation ◽  
Aromatic Hydrocarbons ◽  
Combustion Kinetics ◽  
Surrogate Fuels ◽  
Elimination Reactions ◽  
Kinetics Of

Systematic theoretical investigation of ipso substitution by H on mono-aromatic hydrocarbons (MAHs), bio-oils components relevant to the pyrolysis and combustion kinetics of MAHs for the prediction of PAHs growth and surrogate fuels formulation.

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