A simple differential thermal analysis technique for determining the pressure dependence of solid-liquid and solid-solid transition temperatures

1985 ◽  
Vol 6 (3) ◽  
pp. 275-284 ◽  
Author(s):  
A. J. Easteal ◽  
L. A. Woolf ◽  
F. L. Wilson
2004 ◽  
Vol 19 (8) ◽  
pp. 2262-2267 ◽  
Author(s):  
Sinn-wen Chen ◽  
Hsiu-feng Hsu ◽  
Chih-wei Lin

The liquidus projection of the ternary Sn–Ag–Ni system at the Sn-rich side was determined experimentally. No ternary compound was found, and the ζ–Ag4Sn, Ag3Sn, and Sn existed as the primary solidification phases only in very small compositional portions of the ternary Sn–Ag–Ni system. In more than half of the compositional regime of the ternary system, the Ni3Sn2 phase was the primary solidification phase. The differential thermal analysis technique was used to determine the reaction temperatures and solidification sequences of various Sn-rich Sn–Ag–Ni alloys. Three invariant reactions were found: L = Sn + Ni3Sn4 + Ag3Sn, L + ζ–Ag4Sn = Ni3Sn4 + Ag3Sn and L + Ni3Sn2 = ζ–Ag4Sn + Ni3Sn4. Their reaction temperatures have been determined to be 219, 488, and 516.5 °C, respectively.


1966 ◽  
Vol 39 (2) ◽  
pp. 206-210 ◽  
Author(s):  
R. E. Hammett ◽  
R. E. Wingard ◽  
J. E. Land

Abstract The melting range and growth rate curves for natural rubber crystallites have been studied by the differential thermal analysis technique. The results obtained compare favorably with the growth rate curves obtained by dilatometric techniques. The use of differential thermal analysis revealed details of the crystallite melting which were not apparent when the dilatometer was used; however, no quantitative data on heat effects or the degree of crystallinity were calculated.


2009 ◽  
Vol 46 (3) ◽  
pp. 137-152 ◽  
Author(s):  
Mile Djurdjevic ◽  
Glenn Byczynski ◽  
Carola Schechowiak ◽  
Hagen Stieler ◽  
Jelena Pavlovic

Fuel ◽  
2021 ◽  
Vol 285 ◽  
pp. 119217
Author(s):  
Qiong Mo ◽  
Junjie Liao ◽  
Liping Chang ◽  
Yanna Han ◽  
Alan L. Chaffee ◽  
...  

1992 ◽  
Vol 7 (8) ◽  
pp. 2035-2039 ◽  
Author(s):  
T.G. Holesinger ◽  
D.J. Miller ◽  
S. Fleshler ◽  
L.S. Chumbley

Reactions with alumina and platinum crucibles were studied during the preparation of Bi2Sr2Ca1Cu2Oy “2212” glasses. In particular, reactions with Al2O3 are of interest since alumina is a potential substrate material in applications of this superconductor. Glasses processed using alumina crucibles were completely homogeneous and free of secondary phases although the material contained 2.26 at. % Al in solution. After heat treatments, Al was found in the form of SrCaAlOy particles located primarily along grain boundaries of the 2212 superconducting phase. Platinum contamination was minimal (<0.02 at. %) and no Pt-containing secondary phases were found in amorphous or annealed samples. Glasses made with Pt crucibles were found to contain small amounts of CaO, Sr14−xCaxCu24O41, and 2201 as second phases. Differential thermal analysis (DTA) suggested that the crystallization processes were essentially the same for all samples although the small amount of Al seemed to slow the kinetics leading to the formation of 2212. Neither Al nor Pt was detected within the 2212 phase. The measured superconducting compositions in each annealed sample were nearly the same with identical transition temperatures of 88 K. Overall differences in stoichiometry were accommodated by changes in the number and composition of the secondary phases present.


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