Thermal conductivity measurements and molecular association in a series of alcohol vapors: Methanol, ethanol, isopropanol, and t-butanol

1981 ◽  
Vol 2 (2) ◽  
pp. 115-132 ◽  
Author(s):  
D. J. Frurip ◽  
L. A. Curtiss ◽  
M. Blander
Keyword(s):  
Thermal Conductivity ◽  
Molecular Association ◽  
Conductivity Measurements

Measuring the Thermal Conductivity of Porous, Transparent SiO2 Films With Time Domain Thermoreflectance

2011 ◽  
Vol 133 (6) ◽  
Author(s):  
Patrick E. Hopkins ◽  
Bryan Kaehr ◽  
Leslie M. Phinney ◽  
Timothy P. Koehler ◽  
Anne M. Grillet ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Time Domain ◽  
Optical Measurements ◽  
Conductivity Measurements ◽  
Glass Slides ◽  
Thermally Conductive ◽  
Surface Variability ◽  
Porous Nanomaterials ◽  
Structural Aspects ◽  
Nanoporous Structures

Nanocomposites offer unique capabilities of controlling thermal transport through the manipulation of various structural aspects of the material. However, measurements of the thermal properties of these composites are often difficult, especially porous nanomaterials. Optical measurements of these properties, although ideal due to the noncontact nature, are challenging due to the large surface variability of nanoporous structures. In this work, we use a vector-based thermal algorithm to solve for the temperature change and heat transfer in which a thin film subjected to a modulated heat source is sandwiched between two thermally conductive pathways. We validate our solution with time domain thermoreflectance measurements on glass slides and extend the thermal conductivity measurements to SiO2-based nanostructured films.

Development of Operating Temperature Prediction Method Using Thermophysical Properties Change of Thermal Barrier Coatings

2004 ◽  
Vol 126 (1) ◽  
pp. 102-106 ◽  
Author(s):  
T. Fujii ◽  
T. Takahashi
Keyword(s):  
Thermal Conductivity ◽  
Thermal Barrier Coatings ◽  
Operating Temperature ◽  
Thermal Barrier ◽  
Conductivity Measurements ◽  
Barrier Coatings ◽  
Barrier Performance ◽  
Very High ◽  
General Method ◽  
Exposure Conditions

Thermal barrier coatings (TBCs) have become an indispensable technology as the temperature of turbine inlet gas has increased. TBCs reduce the temperature of the base metal, but a reduction of internal pores by sintering occurs when using TBCs, and so the thermal barrier performance of TBCs is deteriorated. This in turn increases the temperature of the base metal and could shorten its lifespan. The authors have already clarified by laboratory acceleration tests that the deterioration of the thermal barrier performance of TBCs is caused by a decrease in the noncontact area that exists inside TBCs. This noncontact area is a slit space that exists between thin layers and is formed when TBCs are coated. This paper examines the relations between the decrease of the noncontact area and the exposure conditions, by measuring the thermal conductivity and the porosity of TBCs exposed to the temperatures that exist in an actual gas turbine, and derives the correlation with exposure conditions. As a result, very high correlations were found between the thermal conductivity and exposure conditions of TBCs, and between the porosity and exposure conditions. A very high correlation was also found between the thermal conductivity and porosity of TBCs. In addition, techniques for predicting TBC operating temperature were examined by using these three correlations. The correlation of diameter and exposure conditions of the gamma prime phase, which exists in nickel base super alloys, is used as a general method for predicting the temperature of parts in hot gas paths. This paper proposes two kinds of operating temperature prediction methods, which are similar to this general method. The first predicts the operating temperature from thermal conductivity measurements of TBCs before and after use, and the second predicts the operating temperature from thermal conductivity measurements of TBCs after use and porosity measurements before use. The TBC operating temperatures of a combustor that had been used for 12,000 hours with an actual E-class gas turbine were predicted by these two methods. The advantage of these methods is that the temperature of all parts with TBC can be predicted.

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