The accumulation and intracellular compartmentation of cadmium, lead, zinc and calcium in two earthworm species (Dendrobaena rubida and Lumbricus rubellus) living in highly contaminated soil

1982 ◽  
Vol 75 (2) ◽  
pp. 269-285 ◽  
Author(s):  
A. J. Morgan ◽  
B. Morris
2018 ◽  
Vol 13 (2) ◽  
pp. 113-122 ◽  
Author(s):  
Dzerassa N. Chigoeva ◽  
Inna Z. Kamanina ◽  
Svetlana P. Kaplina

The long history of development of deposits of lead-zinc ores of the Sadonsky mining region led to the formation of extensive halos of chemical pollution of surface watercourses. Aim. The aim of this study is to monitor surface watercourses in the area of the Unalsky tailing dumps and the Kholst deposit by points of sampling of 1992-2004. Sampling was conducted in the summer of 2016. Methods. The content of heavy metals of 2 and 3 hazard classes (Pb, Cd, Ni, Zn and Cu) was studied by atomic absorption. The contribution of the Unaldon River and Unalsky tailing dump to the pollution of the Ardon River. Results. The highest content of cadmium, lead and zinc, significantly exceeding the maximum permissible concentrations (MPC) in the water bodies of cultural and domestic use is found in the Ardon River down from the Unalsky tailing dump. The flow of heavy metals into the Unaldon River with adit waters compared with the observation period of 1992-2004 decreased noticeably. In conditions of a reduction in the production capacity of mining and processing enterprises, the leaching of heavy metals from mountain dumps and excavations make an insignificant contribution to the pollution of the Ardon River in comparison with the Unalsky tailing dump. Conclusion. The state of the Ardon River down from the discharge from the tailing dump corresponds to the "environmental disaster" category. The condition of the rivers Mayramdon and Unaldon according to the content of heavy metals corresponds to a "relatively satisfactory" type.


2020 ◽  
Vol 231 (10) ◽  
Author(s):  
C. Amoah-Antwi ◽  
J. Kwiatkowska-Malina ◽  
E. Szara ◽  
S. Thornton ◽  
O. Fenton ◽  
...  

Abstract Organic sorbents alter physicochemical soil properties and mitigate heavy metal (HM) bioavailability. However, some sorbents are labile and, therefore, introduce the risk of HM release into soil after mineralisation. Before field application, new stable organic sorbents such as woodchip biochar (BIO) and brown coal waste (BCW) need to be tested and compared with standard organic amendments like farmyard manure (FYM). An incubated pot experiment was conducted to investigate the efficacy of FYM, BIO and BCW (added to soil in pots at 5 and 10% w/w) to alter soil physicochemical properties and mitigate bioavailability of Cd, Pb and Zn spiked in treatments at different doses (in mg kg−1); 0 (not spiked), 1 (1 Cd, 70 Pb, 100 Zn) and 2 (3 Cd, 500 Pb, 700 Zn), and incubated for 9 weeks. At the end of the experiment, the EDTA-extractable HM fractions, pH, cation exchange capacity (CEC) and specific surface area (SSA, to check trends) were determined in all treated soils. Results showed that FYM, BCW and BIO generally improved all soil properties (except reduced pH from BCW and apparent SSA reduction from FYM) and accounted for respective maximum abatements of Cd (50.2, 69.9 and 25.5%), Pb (34.2, 64.3 and 17.4%) and Zn (14.9, 17.7 and 11.8%) bioavailability in soil. FYM and BCW were more effective at 10% w/w especially in the low contaminated soil, whereas the highest efficacy for BIO was at 5% w/w and in the high contaminated soil. The efficacies of sorption by the organic sorbents varied for different HMs and were in the orders: BCW > FYM > BIO for Cd, FYM > BCW > BIO for Pb and BIO > BCW > FYM for Zn. Soil pH and CEC were strongly correlated with HM bioavailability in all treatments and implied that immobilisation of HMs occurred via complex formation, ion exchange and pH-dependent specific adsorption. All three sorbents were beneficial as soil amendments, and in terms of HM mitigation, BCW had the highest efficacy, followed by FYM and then BIO. Considering the documented high soil stability of BCW and BIO, these results are promising for further trialling at field scale.


2021 ◽  
Vol 11 (24) ◽  
pp. 11822
Author(s):  
Marija Đurić ◽  
Primož Oprčkal ◽  
Vesna Zalar Serjun ◽  
Alenka Mauko Pranjić ◽  
Janez Ščančar ◽  
...  

Paper-ash is used for remediation of heavily contaminated soils with metals, but remediation efficiency after longer periods has not been reported. To gain insights into the mechanisms of immobilization of cadmium (Cd), lead (Pb), and znic (Zn), a study was performed in the laboratory experiment in uncontaminated, artificially contaminated, and remediated soils, and these soils treated with sulfate, to mimic conditions in contaminated soil from zinc smelter site. Remediation was performed by mixing contaminated soil with paper-ash to immobilize Cd, Pb, and Zn in the geotechnical composite. Partitioning of Cd, Pb, and Zn was studied over one year in seven-time intervals applying the sequential extraction procedure and complementary X-ray diffraction analyses. This methodological approach enabled us to follow the redistribution of Cd, Pb, and Zn over time, thus, to studying immobilization mechanisms and assessing the remediation efficiency and stability of newly formed mineral phases. Cd, Pb, and Zn were effectively immobilized by precipitation of insoluble hydroxides after the addition of paper-ash and by the carbonization process in insoluble carbonate minerals. After remediation, Cd, Pb, and Zn concentrations in the water-soluble fraction were well below the limiting values for inertness: Cd by 100 times, Pb by 125 times, and Zn by 10 times. Sulfate treatment did not influence the remediation efficiency. Experimental data confirmed the high remediation efficiency and stability of insoluble Cd, Pb, and Zn mineral phases in geotechnical composites.


Author(s):  
Е.О. ЛАРЬКИНА ◽  
Д.В. СВИЩУК ◽  
Е.П. ЛАПЫНИНА

Проблема и цель. Целью научного исследования является изучение влияния антропогенных и биотических факторов на популяцию медоносной пчелы Рязанской области. Методология. Объект исследования: пчелиные семьи пасек разных районов Рязанской области, продукты пчеловодства. Для исследования были выбраны четыре участка пасеки, расположенные в границах Рязанской области. Опытные группы (далее ОГ) сформировали следующие участки: Кадомский район, д. Большое Лунино (54°34'58'' N, 42°21'25'' E) – ОГ №1; Захаровский район, д. Фурмакино (54°31'18'' N, 38°57'59'' E) – ОГ №2; Рыбновский район, с. Алешня (54°65'23'' N, 39°34'44'‘ E) – ОГ №3. В качестве контрольной группы (далее КГ) выбрана экспериментальная пасека Рыбновского района, с. Булыгино (54°66'58'' N, 39°26'52'' E). Пробоподготовка осуществлялась в период начала активного медосбора, путем отбора трех образцов каждого природного объекта. Образцы медоносных пчел отбирались от 5 пчелиных семей с каждого исследуемого участка, а также проводился отбор проб воды, медоносных растений и почвы. Для анализа степени пораженности заболеваниями нозематоз и варроатоз от каждой исследуемой пчелиной семьи было отобрано по 50-60 рабочих пчел. Результаты. Проведен сравнительный анализ на содержание токсичных металлов в образцахводы, почвы, теле медоносной пчелы, медоносных растений, пыльцевой обножки. Полученные данные свидетельствуют о том, что содержание кадмия, свинца, цинка и меди в образцах воды, медоносных растений, пыльцевой обножки и теле медоносных пчел находятся в предельно допустимой концентрации. Анализ образцов почвы показал превышение допустимой концентрации во всех исследуемых районах, за исключением Кадомского. Заключение. Загрязнение тяжелыми металлами прослеживается в цепочке: почва – медоносные растения – медоносная пчела – продукты пчеловодства в образцах Захаровского р-на, д. Фурмакино. В связи с этим размещение пасек в местах с повышенным содержанием токсичных элементов в природной среде может создавать угрозу интоксикации медоносных пчел и заноса этих металлов в продукты пчеловодства. Problem and goal. The purpose of the research is to study the infuence of anthropogenic and biotic factors on the population of the honey bee of the Ryazan region. Methodology. Object of research: bee families of apiaries of diferent districts of the Ryazan region, bee products. Four apiary plots located within the boundaries of the Ryazan Region were selected for the study. The experimental groups (hereinafter referred to as OG) formed the following sections: Kadomsky district, Bolshoe Lunino village (54°34 '58" N, 42°21'25" E) – OG No. 1, Zakharovsky district, Furmakino village (54°31'18" N, 38°57'59" E) – OG No. 2, Rybnovsky district, Aleshnya village (54°65'23" N, 39°34'44" E) - OG No. 3. As a control group (hereinafter referred to as the KG), the experimental apiary of the Rybnovsky district, p. Bulygino (54°66'58" N, 39°26'52" E). Sample preparation was carried out during the beginning of the active honey collection, by selecting three samples of each natural object. Samples of honey bees were taken from 5 bee colonies from each study site, as well as water, honey plants and soil samples. To analyze the degree of infection with nosematosis and varroatosis from each studied bee family, 50-60 worker bees were selected. Results. A comparative analysis of the content of toxic metals in samples of water, soil, honeybee body, honey plants, pollen pollen was carried out. The data obtained indicate that the content of cadmium, lead, zinc and copper in the samples of water, honey plants, pollen pollen and honey bees are in the maximum permissible concentration. The analysis of soil samples showed an excess of the permissible concentration in all the studied areas, with the exception of Kadomsky. Conclusion. Heavy metal contamination can be traced in the chain: soil-honey plants – honey bee-bee products in the samples of Zakharovsky district, Furmakino village. In this regard, the placement of apiaries in places with a high content of toxic elements in the natural environment can pose a threat to the intoxication of honey bees and the introduction of these metals into beekeeping products.


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