Determination of nitrate in palladium electroplating baths with a nitrate-ion selective electrode by precipitation titration or direct potentiometry

1983 ◽  
Vol 314 (6) ◽  
pp. 560-562 ◽  
Author(s):  
M. Gei\ler ◽  
R. Kunze
1972 ◽  
Vol 22 (2) ◽  
pp. 119-122 ◽  
Author(s):  
J.N. Driscoll ◽  
A.W. Berger ◽  
J.H. Becker ◽  
J.T. Funkhouser ◽  
J.R. Valentine

1981 ◽  
Vol 27 (8) ◽  
pp. 1435-1438 ◽  
Author(s):  
G B Levy

Abstract The advent of ion-selective electrodes made possible the potentiometry of sodium in serum and plasma. These methods were based on dilution of serum, as done in flame photometry, and the results were identical. Analysis of whole blood precludes dilution and so "direct" potentiometry was developed. Results by this technique are variable but tend to compensate for the spurious hyponatremias found by the "indirect" dilution methods due to displacement of volume by lipids and protein. However, there is no unambiguous theoretical basis on which to choose between the various direct ion-selective-electrode techniques and instruments. As an alternative, I propose use of current indirect methods, with numerical correction for the shift in normal sodium values in the presence of abnormal lipid and (or) protein. A table was constructed for making such corrections.


1988 ◽  
Vol 22 (6) ◽  
pp. 249-256 ◽  
Author(s):  
Yoshiko Fujiwara ◽  
Shinji Ohsawa ◽  
Kunihiko Watanuki ◽  
Bokuichiro Takano

Author(s):  
Геннадий Иванович Мантров ◽  
Мариана Александровна Феофанова ◽  
Егор Максимович Грачев

Описана конструкция и электроаналитические характеристики ионселективного электрода (ИСЭ) для количественного определения метформина. В качестве электродноактивных соединений в ИСЭ были использованы ионные ассоциаты метформина с фосфорновольфрамовой(ФВК), фосфорномолибденовой(ФМК) и кремний вольфрамовой кислотами (КВК). Проведено потенциометрическое определение метформина в фармацевтических препаратах. The construction and electroanalytical characteristics of ion-selective electrode (ISE) for metformin are described. Ion pair of metformin with heteropolyacids were tested as electroactive materials for ionometric sensor controls. The ISE was used for direct potentiometry of metformin.


2006 ◽  
Vol 71 (12) ◽  
pp. 1345-1352 ◽  
Author(s):  
Marian Isvoranu ◽  
Constantin Luca ◽  
Maria Pleniceanu ◽  
Cezar Spinu

This paper presents experimental and theoretical data regarding the design, characterization and analytical applications of a non-expensive, liquid-membrane ion-selective electrode for Pb2+ ions. The membrane is a solution of the active complex formed by Pb2+ ions with dibenzo-18-crown-6-ionophore (DB-[18]-C-6) extracted in propylene carbonate (PC). The successful application of the developed electrode for the determination of Pb2+ ions in aqueos solution samples by direct potentiometry and potentiometric titration is presented. For the presented analytical results, there are insignificant systematic errors between the direct potentiometric method with the developed ion-selective electrode and atomic absorption spectrometry. .


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