Design and use of a collector for the in situ isolation of particulate trace organic species in precipitation

1987 ◽  
Vol 36 (1-2) ◽  
pp. 171-192 ◽  
Author(s):  
M. A. Mazurek ◽  
B. R. T. Simoneit ◽  
L. J. Standley ◽  
D. Friedman ◽  
C. Beeman
1984 ◽  
Vol 4 (4) ◽  
pp. 317-333
Author(s):  
James F. Osborn ◽  
Suresh Santhanam ◽  
Cliff I. Davidson ◽  
Richard D. Flotard ◽  
Joseph R. Stetter

2008 ◽  
Vol 42 (13) ◽  
pp. 3059-3075 ◽  
Author(s):  
M KLEEMAN ◽  
M ROBERT ◽  
S RIDDLE ◽  
P FINE ◽  
M HAYS ◽  
...  

2010 ◽  
Vol 12 (1) ◽  
pp. 225-233 ◽  
Author(s):  
Michael B. Henjum ◽  
Raymond M. Hozalski ◽  
Christine R. Wennen ◽  
William Arnold ◽  
Paige J. Novak

2008 ◽  
Vol 42 (24) ◽  
pp. 6152-6154 ◽  
Author(s):  
Michael J. Kleeman ◽  
Michael A. Robert ◽  
Sarah G. Riddle ◽  
Philip M. Fine ◽  
Michael D. Hays ◽  
...  

2015 ◽  
Vol 1773 ◽  
pp. 21-26
Author(s):  
Nicolas Delaporte ◽  
Karim Zaghib ◽  
Daniel Bélanger

ABSTRACTBromophenyl moieties were attached to the carbon-coated LiFePO4 (LiFePO4/C) surface by spontaneous reduction of in-situ generated 4-bromobenzene diazonium ions in organic media. The presence of the surface organic species on the grafted LiFePO4/C powders was confirmed by X-ray photoelectron spectroscopy. Thermogravimetric analyses revealed a low loading (lower than 1 wt. %) of grafted molecules. The electrochemical characterization of the LiFePO4/C cathodes showed that a low loading of bromophenyl groups at the LiFePO4/C surface can enhance the rate of Li+ extraction, presumably due to the decrease of the LiFePO4/C agglomerate size and an increase of the wettability of the electrode. On the other hand, poor performances were obtained using the grafted cathode material with the highest loading of bromophenyl moieties.


2007 ◽  
Vol 330-332 ◽  
pp. 427-430
Author(s):  
Gui Qiu Zheng ◽  
Xu Dong Li ◽  
Xiao Min Wang ◽  
Su Hong Yu ◽  
Zhong Wei Gu ◽  
...  

Synthesis of hydroxyapatite (HA) in organic solutions has received extensive attention in recent years with an attempt to obtain HA of a nanometer level. In this preliminary study, we demonstrated that organic-HA nanocomposites could also be achieved with one step method via in situ mineralization and subsequent crosslinking of organic species. This design was realized through in situ synthesis of hydroxyapatite in poly(vinyl alcohol) and acrylic acid aqueous solution as an organic template. The aforementioned organic-inorganic nanocomposites were analyzed by using X-ray diffraction, Fourier-transform infrared spectroscopy, scanning electrical microscopy, thermal analysis. The comparative structural measurements were also conducted with the synthesized HA with absence of the organic template. The results indicated that the existence of organic species effectively inhibits the growth of calcium phosphate and that relatively pure HA can be obtained in sintered composite products. The present study provides a direct and versatile route for fabrication of nanocomposite biomaterials.


1992 ◽  
Vol 284 ◽  
Author(s):  
H. Sakaue ◽  
T. Nakasako ◽  
K. Nakaune ◽  
T. Kusuki ◽  
A. Miki ◽  
...  

ABSTRACTIn order to fill high quality insulators into narrower spaces in advanced metallizationthe digital CVD (Chemical Vapor Deposition) of multilayer stacked Si oxide and nitride films was studied. Reaction of TES (triethylsilane) with hydrogen (H) atoms was also found to lead to conformal CVD of Si film involving organic species. This reaction took place only on the surface reaction. In-situ FTIR studies reveal that H atoms react with Si-C2H5 bonds in TES and thus generate strong Si-CH3 bonds and weak Si-H bonds, thereby liberating H2 and forming the organic Si film on the surface, and the surface reaction is dominated by the thermal effect from the substrate. Then Si oxide or nitride films were formed by the digitaCVD which repeated a cycle of deposition of this film with subsequent oxidation or nitridation. Oxide film integrity was improved greatly by removing included organic bonds in the TES/H reaction film by exposing the film to H atoms before the oxidation step. Thus electrically excellent multilayer stacked oxide and nitride films were obtained in a deep trench.


2007 ◽  
Vol 41 (6) ◽  
pp. 1962-1969 ◽  
Author(s):  
Sarah G. Riddle ◽  
Michael A. Robert ◽  
Chris A. Jakober ◽  
Michael P. Hannigan ◽  
Michael J. Kleeman

1997 ◽  
Vol 51 (5) ◽  
pp. 673-677 ◽  
Author(s):  
Yasuo Iida ◽  
Masamichi Furukawa ◽  
Kazumi Kato ◽  
Hisashi Morikawa

The phase transformation from a gel of titanium alkoxide to crystalline anatase was observed in situ by anti-Stokes Raman scattering. Utilization of anti-Stokes scattering eliminates interference from the fluorescence of decomposing organic residuals during the pyrolysis process. The anti-Stokes Raman spectra suggest a highly disordered structure during the pyrolysis process. The structure of the titania gel, which is characterized by broad Raman peaks around 440 and 620 cm−1, was transformed into the amorphous structure by increasing the temperature up to 200–300 °C. This amorphous structure is supported by a flat Raman spectrum lacking specific features in the wavenumber region from 200 to 1000 cm−1. A partially crystallized gel also exhibits the further progress of amorphization during the pyrolysis process, which is explained by the disordering of the local structure of the gel due to the generation of pyrolyzed organic species.


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